Semi-humic composition and methods of use thereof

ABSTRACT

This disclosure relates to a semi-humic composition comprising one or more humic substance which has been chemically interacted with one or more organic non-humic nitrogenous molecules, methods of use thereof, and a process for obtaining the same. The compositions provided herein are useful for enhancing crop growth, and in particular, in the area of organic farming.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims the benefit under 35 U.S.C. 119(e) to U.S. Provisional Application Ser. Nos. 62/334,248, filed May 10, 2016, and 62/347,555, filed Jun. 8, 2016, where the contents of each is incorporated herein by reference in its entirety.

FIELD

This disclosure relates to a semi-humic composition comprising one or more humic substances which has been chemically interacted with one or more organic non-humic nitrogenous molecules, methods of use thereof, and a process for obtaining the same. The compositions provided herein are useful for enhancing crop growth, in particular in the area of organic farming.

BACKGROUND

Farmers typically employ agricultural fertilizers to maintain good yields, product quality and profitability. Organic farmers, like any other, need to provide nitrogen to their crops, but also must adhere to strict requirements to ensure that the nitrogen source is approved for use in organic crop farming. In addition, determining which organic fertilizer material to use, how much to apply and when to apply it, is vital, and is even considered more challenging organically than it is conventionally. One major challenge when using organic nitrogen as a fertilizer is synchronizing the timing of mineralization with plant demand as nitrogen mineralization into ammonium and nitrate forms is required before uptake by most plants. Failure to synchronize nitrogen mineralization with crop uptake can lead to plant nutrient deficiencies, excessive soil nitrogen beyond the growing season, and the potential for excessive nitrate leaching.

Manures and composts, which are commonly used as nitrogen sources in organic farming, contain and release nitrogen slowly and in varying amounts. As such, it is difficult to use them efficiently for optimal crop growth. In addition, as compost ages, the availability of the nitrogen it contains tends to decrease. An animal-based organic nitrogen fertilizer, like blood meal, may “burn” delicate vegetable roots if applied without mixing into the soil, or too close to established plants. In addition to burning roots, animal-based fertilizers may also attract rats, raccoons, opossums, and other unwelcome nocturnal pests.

SUMMARY

The present disclosure relates to a semi-humic composition comprising one or more humic substances which has been chemically interacted with organic non-humic nitrogenous molecules. It is contemplated that the semi-humic composition disclosed herein has a unique chemical make-up which provides, in one embodiment, an increased, more reliable and predictable rate of mineralization in soil. In addition, the semi-humic composition described herein results in a more rapid uptake of nitrogen in the crop, as well as improved plant growth, development and yield.

In one embodiment, the semi-humic composition disclosed herein may be obtained by a process comprising the steps of:

(a) heating an aqueous composition of an organic non-humic nitrogenous source in the presence of a base to a temperature of about 100° F. or higher;

(b) adding leonardite ore or other soft brown coal to the composition and mixing to provide a liquid portion and a solids portion; and

(c) separating the liquid portion from the solids portion to provide the semi-humic composition.

In certain embodiments, step (a) is performed at a temperature of about 160° F. or higher for at least about 1 hour or more, or at least about 2 hours. In certain embodiments, step (b) is performed at a temperature of about 160° F. or higher for at least about 30 minutes, or at least about 1 hour or more, or at least about 2 hours.

In one embodiment, the semi-humic composition described herein may be obtained by a process which comprises:

(a) heating an aqueous composition of leonardite ore or other soft brown coal in the presence of a base to a temperature of about 160° F. or higher to provide a composition having a liquid portion and a solids portion;

(b) mixing an organic non-humic nitrogenous source with the composition of step (a) and heating to a temperature of at least about 160° F. for at least about 2 hours, and optionally further removing solids, to provide the semi-humic composition. In certain embodiments, step (a) is performed at a temperature of about 160° F. or higher for at least about 30 minutes, or at least about 1 hour or more, or at least about 2 hours. In certain embodiments, the process further comprises adding a non-humic organic carbon source, such as an organic acid. In certain embodiments, the process further comprises the step of separating the liquid portion from the solids portion of step (a). In such instances, the mixing of step (b) comprises mixing the organic non-humic nitrogenous source with the liquid portion of step (a).

It is contemplated that by performing the processes as described herein, the organic non-humic nitrogenous source is at least partially hydrolyzed and/or broken down into reactive organic constituents which then chemically interacts with humic material obtained from the leonardite ore or other soft brown coal. As such, also provided herein is a semi-humic composition obtainable by the processes disclosed herein.

The present disclosure also relates to methods for increasing the rate of nitrogen mineralization in soil, increasing nitrogen content in a crop, and increasing the rate of nitrogen uptake by a crop.

In addition, the present disclosure relates to methods for enhancing crop growth and yield using an organic nitrogen source.

BRIEF DESCRIPTION OF THE DRAWINGS

Other features and advantages will occur from the following description and the accompanying drawings.

FIGS. 1A and 1B show a synthetic flow chart for semi-humic composition.

FIG. 2 shows a Venn Diagram displaying the molecular formula overlap between the samples of Example 2. The unique molecular formulas identified in the semi-humic composition are displayed in Table 5B in their neutral sum format.

FIGS. 3A, 3B, 4A and 4B show Van Krevelen Diagrams of i) the semi-humic composition overlayed with a standard humic composition and blood meal alone (FIGS. 3A and 4A) and ii) the semi-humic composition alone (FIGS. 3B and 4B). FIG. 5 shows the percent of total nitrogen mineralized over time using the semi-humic composition.

FIG. 6 shows the mean root weight of pepper at harvest as affected by Composition 1 compared to blood meal alone and the untreated control.

FIG. 7 shows the mean percent nitrogen content in pepper shoots at harvest as affected by Composition 1 and blood meal alone.

DETAILED DESCRIPTION Definitions

It is to be understood that this disclosure is not limited to particular embodiments described, as such may, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular embodiments only, and is not intended to be limiting, since the scope of the present disclosure will be limited only by the appended claims.

LIST OF ABBREVIATIONS

-   -   mg Milligrams     -   ESI Electrospray ionization     -   LC-ESI- liquid chromatography-electrospray ionization-     -   MS tandem mass spectrometry     -   O:C Oxygen to carbon ratio     -   H:C Hydrogen to carbon ratio     -   FID Flame ionization detector     -   FTCIR Fourier transform ion cyclotron resonance     -   w/w Weight/weight     -   m/z mass-to-charge ratio     -   MS Mass spectrometry     -   Kg Kilograms     -   mL Milliliter     -   g Gram     -   μg Microgram     -   mm Millimeter     -   cm Centimeter     -   Ac/ac Acre     -   Ha Hectare     -   Da Dalton     -   s Seconds     -   wt Weight     -   L Liter     -   lbs/lb Pounds     -   mM Millimolar     -   Gal/gal Gallon     -   N Nitrogen     -   V Volume     -   μL Microliter     -   M Molar     -   H Hour     -   CDFA California Department of Food & Agriculture     -   ANOVA Analysis of Variance

It must be noted that as used herein and in the appended claims, the singular forms “a”, “an”, and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to “a nutrient” includes a plurality of nutrients.

Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this disclosure belongs. As used herein the following terms have the following meanings.

As used herein, the term “comprising” or “comprises” is intended to mean that the compositions and methods include the recited elements, but not excluding others. “Consisting essentially of” when used to define compositions and methods, shall mean excluding other elements of any essential significance to the combination for the stated purpose. Thus, a composition consisting essentially of the elements as defined herein would not exclude other materials or steps that do not materially affect the basic and novel characteristic(s) claimed. “Consisting of” shall mean excluding more than trace elements of other ingredients and substantial method steps. Embodiments defined by each of these transition terms are within the scope of this disclosure.

The term “about” when used before a numerical designation, e.g., temperature, time, amount, and concentration, including range, indicates approximations which may vary by (+) or (−) 10%, 5% or 1%.

Humic substances (HS) are defined by the IHSS (International Humic Substances Society) as complex, heterogeneous mixtures of polydispersed materials formed by biochemical and chemical reactions during the decay and transformation of plant and microbial remains (a process called humification). HS are naturally present in soil, water, peats, brown coals and shales. Traditionally these substances have been isolated into three fractions: humic acid, fulvic acid and humin. These fractions are operationally defined based on solubility in basic and acidic solutions. Leonardite, a brown coal, is known to be rich in humic acid.

As used herein, the term “semi-humic composition” is intended to refer to a composition which comprises molecules from both humic substances and non-humic substances, such as molecules originating from an organic non-humic nitrogenous source (e.g., blood meal) and optionally additional non-humic carbon sources (e.g., an organic acid). In certain embodiments, the term “semi-humic” is intended to refer to a composition which comprises both humic and non-humic organic carbon molecules which have been transformed into new molecules containing carbon from both sources.

The term “organic non-humic nitrogenous molecules” is intended to refer to molecules which are present in plant and/or animal by-products (e.g., derived from fresh and or partially decomposed plant material, animal manure, animal and/or fish parts). The organic non-humic nitrogenous molecules are typically considered to be proteins, peptides, amines, amides and/or amino acids. Suitable sources for non-humic nitrogenous molecules includes, but are not limited to, those derived from blood meal, intestines, bone meals, feathers, crustacean, microbial, bacterial, protozoan, chromistan, fungal biomass, fresh corn meal, soy meal and/or other plant seed materials. See, e.g., Mikkelsen, et al. Better Crops, 2008, 92(4), 16-19.

The term “chemically interacted” is intended to generally refer to all types of chemical bonding, including and not limited to, non-covalent (e.g., hydrogen or ionic) and/or covalent bonding. In certain embodiments, the chemical interaction is a combination of covalent and non-covalent bonding interactions between the components obtained from the organic non-humic nitrogen source and the components obtained from the humic substance (e.g., leonardite ore or other soft brown coal).

As used herein, the term “fertilizer” is intended to refer to is any material of natural (organic) or synthetic origin (other than liming materials) that is applied to soils or to plant tissues (usually leaves) to supply one or more plant nutrients essential to the growth of plants. An “organic” type fertilizer is primarily derived from decomposed or processed plant and/or animal by-products (e.g., manure or fish emulsion). The fertilizer can comprise liquid and/or solid components and may contain one or more additional micronutrients, such as iron, manganese, molybdenum, zinc, and/or copper.

The term “applying” or “applied” is intended to refer to any suitable method for applying the semi-humic composition and a fertilizer to soil. The term is intended to encompass methods for applying liquid, solid, or other form or mixture thereof to the soil or plant (e.g., foliar application). In certain embodiments, the “applying” or “applied” comprises one or more of spraying, flooding, soil injection and/or chemigation, and can be to the soil at any point or to the plant or crop (e.g., foliar application).

The term “nitrogen mineralization” is intended to refer to the process wherein nitrogen is converted to plant-usable ammonium and nitrate forms.

Semi-Humic Composition

Disclosed herein is a semi-humic composition comprising one or more humic substance which has been chemically interacted with one or more organic non-humic nitrogenous molecules. The one or more organic non-humic nitrogenous molecules are considered to be, in general, molecules such as peptides or other amine, amide, and/or amino acid containing molecules. The source for the one or more organic non-humic nitrogenous molecules can be derived from any fresh or decomposed plant and/or animal by-product. In certain embodiments, the one or more organic non-humic nitrogenous molecules is derived from plant material, such as but not limited to, fungal biomass, fresh corn meal, soy meal and/or other plant seed materials. In another embodiment, the one or more organic non-humic nitrogenous molecules is derived from animal material. The animal material can comprise any one or more of animal waste (e.g., manure) or animal parts, such as but not limited to, blood meal, intestines, bone meals, feathers, crustaceans and/or fish. Other suitable organic non-humic nitrogenous materials are known in the art (see, e.g., Mikkelsen, et al. Better Crops, 2008, 92(4), 16-19).

In certain embodiments, it is contemplated that the one or more organic non-humic nitrogenous molecules in the semi-humic composition described herein are, at least in large part, covalently bonded to the humic substance (including chelation). However, it may be also be that one or more organic non-humic nitrogenous molecules have been chemically interacted with the humic substance via non-covalent interactions such as hydrogen bonding, coordination, ionic bonding, Van der Waals forces and/or hydrophobic interactions.

As shown in Example 1 below, the actual humic-like content of the semi-humic composition as disclosed herein is almost twice as large as the theoretically expected value, which assumes 100% organic extraction of leonardite. This suggests that the process described herein results in chemical interactions, or complexation, between molecules derived from non-humified organic matter (e.g., blood meal) and humified leonardite-derived organic matter, thus resulting in the semi-humic composition. In certain embodiments, the semi-humic composition comprises at least about 5% humic acid as calculated via the CDFA method. In other embodiments, the semi-humic composition comprises at least about 6%, or at least about 7%, or at least about 8%, or at least about 9%, or at least about 10%, or at least about 11%, or at least about 12%, or at least about 13%, or at least about 14%, or at least about 15%, or at least about 16%, or at least about 17%, or at least about 18%, or at least about 20%, or from about 10 to about 20%, or from about 15 to about 20%, or from about 5 to about 12% humic acid as calculated via the CDFA method.

The increase in % weight of the humic-like component is contemplated to be due, at least in part, to the organic non-humic nitrogenous component forming a complex with the compounds obtained from the leonardite ore or other soft brown coal during the humic acid extraction process. It is therefore contemplated that this complex formation is a result of the presence of organic non-humic nitrogenous molecules during the mixing step. Accordingly, other compositions containing leonardite ore or other soft brown coal, or an extract thereof, and another organic non-humic nitrogenous component would not contain the semi-humic composition described herein simply by adding the two components to the soil, or even in a single composition before application to soil.

The amount of nitrogen in the semi-humic composition typically ranges from about 1% to about 20%, or is at least about 3%, or at least about 4%, or at least about 5%, or at least about 8%, or is at least about 10%, or is at least about 15%, or is at least about 20%. However, the amount of nitrogen in the semi-humic composition can be varied based on the amount of organic non-humic nitrogenous source used in the process for obtaining the semi-humic composition. In certain embodiments, the amount of nitrogen in the semi-humic composition is about 3-4%.

In certain embodiments, the amount of nitrogen in the semi-humic composition can be increased by implementing a higher temperature and/or longer mixing time. For example, in certain embodiments, a semi-humic composition having at least about 3% solubilized nitrogen can be prepared by performing the mixing step at a temperature at or above 160° F. for at least about 2 hours. Further, in certain embodiments, the pH of the mixing step should be at least about 14 such that the mixing can be performed for a sufficient amount of time (i.e., at least about 2 hours).

In one embodiment, provided is a semi-humic composition characterized as having from about 30 to about 40% of molecules classified as lipid, protein and other aliphatic by FTICR-MS. The lipid, protein and other aliphatic region of a Van Krevelen diagram is typically defined as those molecules exhibiting a H:C of between about 1.5 and about 2.2, and exhibiting a O:C of between 0 and about 0.67 by FTICR-MS. Accordingly, also provided herein is a semi-humic composition characterized as having about 37% of molecules exhibiting a H:C of between about 1.5 and about 2.2, and exhibiting a O:C of between 0 and about 0.67 by FTICR-MS. In certain embodiments, provided is a semi-humic composition characterized as having about 30%, or about 32%, or about 34%, or about 35%, or about 37%, or about 38% of molecules classified as Lipid, protein and other aliphatic by FTICR-MS.

In some embodiments, the semi-humic composition is characterized as having from about 25 to about 30% of molecules classified as lignin by FTICR-MS. The lignin region of a Van Krevelen diagram is typically defined as those molecules exhibiting a H:C of between about 0.7 and about 1.5, and exhibiting a O:C of between 0.1 and about 0.67 by FTICR-MS. Accordingly, also provided herein is a semi-humic composition characterized as having about 26% of molecules exhibiting a H:C of between about 0.7 and about 1.5, and exhibiting a O:C of between 0.1 and about 0.67 by FTICR-MS. In certain embodiments, provided is a semi-humic composition characterized as having about 25%, or about 26%, or about 27%, or about 28% of molecules classified as lignin by FTICR-MS.

In some embodiments, the semi-humic composition is characterized as having from about 5 to about 10% of molecules classified as condensed aromatic by FTICR-MS. The condensed aromatic region of a Van Krevelen diagram is typically defined as those molecules exhibiting a H:C of between about 0.2 and about 0.7, and exhibiting a O:C of between 0 and about 0.67 by FTICR-MS. Accordingly, also provided herein is a semi-humic composition characterized as having about 9% of molecules exhibiting a H:C of between about 0.2 and about 0.7, and exhibiting a O:C of between 0 and about 0.67 by FTICR-MS. In certain embodiments, provided is a semi-humic composition characterized as having about 5%, or about 6%, or about 7%, or about 8%, or about 9%, or about 10% of molecules classified as Condensed Aromatic by FTICR-MS.

In some embodiments, the semi-humic composition is characterized as having about 1 to about 2% of molecules classified as carbohydrate by FTICR-MS. The carbohydrate region of a Van Krevelen diagram is typically defined as those molecules exhibiting a H:C of between about 1.5 and about 2.4, and exhibiting a O:C of between 0.67 and about 1.2 by FTICR-MS. Accordingly, also provided herein is a semi-humic composition characterized as having between about 1-2% of molecules exhibiting a H:C of between about 1.5 and about 2.4, and exhibiting a

O:C of between 0.67 and about 1.2 by FTICR-MS. In certain embodiments, provided is a semi-humic composition characterized as having greater than 1%, or about 1%, or about 1.5%, or about 2%, or about 3%, or about 4% or about 5% of molecules classified as carbohydrate by FTICR-MS.

In some embodiments, the semi-humic composition is characterized as having from about 25% to about 30% of molecules classified as unsaturated hydrocarbon by FTICR-MS. The unsaturated hydrocarbon region of a Van Krevelen diagram is typically defined as those molecules exhibiting a H:C of between about 0.7 and about 1.5, and exhibiting a O:C of between 0 and about 0.1 by FTICR-MS. Accordingly, also provided herein is a semi-humic composition characterized as having between about 25% to about 30% of molecules exhibiting a H:C of between about 0.7 and about 1.5, and exhibiting a 0:C of between 0 and about 0.1 by FTICR-MS. In certain embodiments, provided is a semi-humic composition characterized as about 25%, or about 26%, or about 27%, or about 28%, or about 29% or about 30% of molecules classified as unsaturated hydrocarbon by FTICR-MS.

In one embodiment, provided is a semi-humic composition characterized as having about 35-40% of molecules classified as lipid, protein and other aliphatic and about 25-30% of molecules classified as lignin by FTICR-MS. In one embodiment, provided is a semi-humic composition characterized as having about 35-40% of molecules classified as lipid, protein and other aliphatic, about 25-30% of molecules classified as lignin, about 5-10% of compounds classified as condensed aromatic, and about 1-2% of molecules classified as carbohydrate by FTICR-MS. In one embodiment, provided is a semi-humic composition characterized as having about 35-40% of molecules classified as lipid, protein and other aliphatic, about 25-30% of molecules classified as lignin, about 5-10% of compounds classified as condensed aromatic, about 1-2% of molecules classified as carbohydrate, and about 25-30% of molecules classified as unsaturated hydrocarbon by FTICR-MS.

As shown in the Venn diagram of FIG. 2, a significant percentage of the molecules identified in the semi-humic composition have molecular formulas which are unique to the composition described herein (Table 5B). Accordingly, also provided is a semi-humic composition, wherein the composition is characterized as comprising at least about 50% of the molecular formulas of Table 5B. In certain embodiments, provided is a semi-humic composition, wherein the composition is characterized as comprising at least about 55%, or at least about 60%, or at least about 65%, or at least about 70%, or at least about 75%, or at least about 80%, or at least about 85%, or at least about 90%, or at least about 95% of the molecular formulas of Table 5B. In certain embodiments, provided is a semi-humic composition, wherein the composition is characterized as comprising from about 50-95%, or about 60-95%, or about 70-95% of the molecular formulas of Table 5B.

In one embodiment, the semi-humic composition described herein may be obtained by a process which comprises:

(a) heating an aqueous composition of an organic non-humic nitrogenous source in the presence of a base to a temperature of about 100° F. or higher;

(b) adding leonardite ore or other soft brown coal to the composition and mixing to provide a liquid portion and a solids portion; and

(c) separating the liquid portion from the solids portion to provide the semi-humic composition.

In certain embodiments, step (a) is performed at a temperature of about 160° F. or higher for at least about 1 hour or more, or at least about 2 hours. In certain embodiments, step (b) is performed at a temperature of about 160° F. or higher for at least about 30 minutes, or at least about 1 hour or more, or at least about 2 hours.

In the above process, the amount of nitrogen and carbon components can be tailored based on the ratio of the organic non-humic nitrogenous source and the leonardite ore (or other soft brown coal) used. It is contemplated that the ratio of the organic non-humic nitrogenous source to leonardite ore (or other soft brown coal) can vary from about 1:2 to about 30:1, or about 1:2, about 1:1, about 2:1, about 3:1, about 4:1, about 5:1, about 8:1, about 10:1, about 15:1, about 20:1, or about 30:1. In certain embodiments, the ratio of the organic non-humic nitrogenous source to leonardite ore (or other soft brown coal) is about 3:1.

In certain embodiments, the organic non-humic nitrogenous source (e.g., blood meal) is used in about 15-25% by weight with respect to the total weight of the composition. In other embodiments, the blood meal is used in about 15, or about 20% or about 25% by weight with respect to the total weight of the composition.

In certain embodiments, the leonardite ore or other soft brown coal is used in about 4-8% by weight with respect to the total weight of the composition. In other embodiments, the leonardite ore or other soft brown coal is used in about 4%, about 5%, about 6%, about 7% or about 8% by weight with respect to the total weight of the composition.

In certain embodiments, the amount of water in the composition (by weight with respect to the total weight of the composition) is about 35-80% by weight, or about 55-80% by weight. In certain embodiments, the amount of water is about 35%, or about 40%, or about 45%, or about 50%, or about 55%, or about 60%, or about 65%, or about 70%, or about 75%, or about 80% by weight.

In certain embodiments, the base of step (a) is a strong base (e.g., an Arrhenius base). In certain embodiments, the base of step (a) is one or more bases selected from the group consisting of LiOH, NaOH, KOH, RbOH, CsOH, Ca(OH)₂, Sr(OH)₂, and Ba(OH)₂. In certain embodiments, the about of base employed in the process (by weight with respect to the total weight of the composition) is about 2-12% by weight, or about 2-10% by weight, or about 2-5% by weight, or about 4-5% by weight. In certain embodiments, the amount of base employed in the process (by weight with respect to the total weight of the composition) is about 2%, or about 3%, or about 4%, or about 4.5%, or about 5%, or about 7%, or about 10%, or about 12% by weight.

In certain embodiments, the base employed is potassium hydroxide (KOH). Accordingly, in certain embodiments, the semi-humic composition comprises a percentage of soluble potassium (e.g., K₂O) which is, at least in part, attributed to the base used in the preparation thereof. In certain embodiments, the about of potassium hydroxide employed in the process (by weight with respect to the total weight of the composition) is about 2-12% by weight, or about 2-10% by weight, or about 2-5% by weight, or about 4-5% by weight. In certain embodiments, the amount of potassium hydroxide employed in the process (by weight with respect to the total weight of the composition) is about 2%, or about 3%, or about 4%, or about 4.5%, or about 5%, or about 7%, or about 10%, or about 12% by weight. In certain embodiments, the semi-humic composition comprises about 1%, or about 2%, or about 3%, or about 4%, or about 5%, or about 6% soluble potassium (e.g., K₂O).

In certain embodiments, the temperature of step (a) is greater than about 100° F., or greater than about 100° F., or greater than about 110° F., or greater than about 120° F., or greater than about 130° F., or greater than about 140° F., or greater than about 150° F., or greater than about 160° F. In some embodiments, the heating of step (a) is performed for at least about 30 minutes or more. In some embodiments, the heating of step (a) is performed for about 1 hour or more, or about 2 hours or more, or about 3 hours or more.

In certain embodiments, the temperature of step (b) is greater than about 100° F., or greater than about 100° F., or greater than about 110° F., or greater than about 120° F., or greater than about 130° F., or greater than about 140° F., or greater than about 150° F., or greater than about 160° F. In some embodiments, the mixing of step (b) is performed for at least about 30 minutes or more. In some embodiments, the mixing of step (b) is performed for about 1 hour or more, or about 2 hours or more, or about 3 hours or more.

The separating of step (c) can be accomplished using any method known in the art, including, but not limited to, centrifugation, decanting, filtration, etc., or a combination thereof.

By performing the process, the weight of the humic fraction is increased as determined by the CDFA Humic Acid Method (see, e.g., Example 1). In some embodiments, the liquid portion comprises at least about 50%, or at least about 75%, at least about 100%, at least about 125%, at least about 150%, by weight greater on a carbon basis than the humic acid fraction which would be obtained by performing the process in the absence of the organic non-humic nitrogenous component obtained by step (a).

In another embodiment, the semi-humic composition described herein may be obtained by a process which comprises:

(a) heating an aqueous composition of leonardite ore or other soft brown coal in the presence of a base to a temperature of about 160° F. or higher to provide a composition having a liquid portion and a solids portion;

(b) mixing an organic non-humic nitrogenous source with the composition of step (a) and heating to a temperature of at least about 160° F. for at least about 2 hours, and optionally further removing solids, to provide the semi-humic composition.

In certain embodiments, step (a) is performed at a temperature of about 160° F. or higher for at least about 30 minutes, or at least about 1 hour or more, or at least about 2 hours. In certain embodiments, the pH of step (b) is greater than about 14.

In certain embodiments, the process further comprises the step of separating the liquid portion from the solids portion of step (a). In such instances, the mixing of step (b) comprises mixing the organic non-humic nitrogenous source with the liquid portion of step (a).

In certain embodiments, the pH of the composition at the mixing of step (b) is sufficiently high such that the composition remains a flowable liquid, and is thus able to be mixed with the composition of step (a) for a sufficient amount of time (e.g., at least about 2 hours) at a sufficient temperature (e.g., at least about 160° F.) such that the semi-humic composition is provided. In certain embodiments, the pH of the composition of step (b) is at least about 14 when the organic non-humic nitrogenous source is mixed therewith. In certain embodiments, the pH of the composition is about 14, or greater than about 14, or about 15, or greater than about 15, or about 16, or from about 14-15, or from about 14-16.

It is contemplated that the ratio of the organic non-humic nitrogenous source used in step (b) to leonardite ore (or other soft brown coal) used in step (a) can vary from about 1:2 to about 30:1, or about 1:2, about 1:1, about 2:1, about 3:1, about 4:1, about 5:1, about 8:1, about 10:1, about 15:1, about 20:1, or about 30:1. In certain embodiments, the ratio of the organic non-humic nitrogenous source to leonardite ore (or other soft brown coal) is about 3:1.

In certain embodiments, the organic non-humic nitrogenous source (e.g., blood meal) is used in about 15-25% by weight with respect to the total weight of the composition. In other embodiments, the blood meal is used in about 15, or about 20% or about 25% by weight with respect to the total weight of the composition.

In certain embodiments, the leonardite ore or other soft brown coal is used in about 4-8% by weight with respect to the total weight of the composition. In other embodiments, the leonardite ore or other soft brown coal is used in about 4%, about 5%, about 6%, about 7%, about 7.5% or about 8% by weight with respect to the total weight of the composition.

In certain embodiments, the amount of water in the composition (by weight with respect to the total weight of the composition) is about 35-80% by weight, or about 55-80% by weight. In certain embodiments, the amount of water is about 35%, or about 40%, or about 45%, or about 50%, or about 55%, or about 60%, or about 65%, or about 70%, or about 75%, or about 80% by weight.

In certain embodiments, the base of step (a) is a strong base (e.g., an Arrhenius base). In certain embodiments, the base of step (a) is one or more bases selected from the group consisting of LiOH, NaOH, KOH, RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. In certain embodiments, the about of base employed in step (a) (by weight with respect to the total weight of the composition) is about 5-20% by weight, or about 5-15% by weight, or about 8-10% by weight. In certain embodiments, the amount of base employed in step (a) (by weight with respect to the total weight of the composition) is about 5%, or about 7%, or about 8%, or about 9%, or about 10%, or about 15%, or about 20% by weight of the entire composition.

In certain embodiments, the base employed in step (a) is potassium hydroxide (KOH). Accordingly, in certain embodiments, the semi-humic composition comprises a percentage of soluble potassium (e.g., K₂O) which is, at least in part, attributed to the base used in the preparation thereof. In certain embodiments, the about of potassium hydroxide employed in step (a) (by weight with respect to the total weight of the composition) is greater than about 8% by weight, or about 8-20% by weight, or about 8-15% by weight, or about 8-10% by weight. In certain embodiments, the amount of potassium hydroxide employed in step (a) (by weight with respect to the total weight of the composition) or about 8%, or about 9%, or about 10%, or about 15%, or about 20% by weight of the entire composition. In certain embodiments, the semi-humic composition comprises about 5%, or about 6%, or about 7%, or about 8%, or about 9%, or about 10% soluble potassium (e.g., K₂O).

In certain embodiments of this process, the temperature of step (a) is greater than about 160° F., or greater than about 170° F., or greater than about 180° F., or from about 160° F. to about 180° F. In some embodiments, the heating of step (a) is performed for at least about 30 minutes or more. In some embodiments, the heating of step (a) is performed for about 1 hour or more, or about 2 hours or more, or about 3 hours or more.

The separating can be accomplished using any method known in the art, including, but not limited to, centrifugation, decanting, filtration, etc., or a combination thereof.

In certain embodiments, the temperature of step (b) is greater than about 160° F., or greater than about 170° F., or greater than about 180° F., or from about 160° F. to about 180° F. In some embodiments, the mixing of step (b) is performed for about 2 hours or more, or about 3 hours or more. In certain embodiments, the temperature is at or greater than about 160° F. for at least 2 hours. In certain embodiments, the temperature is from about 160° F. to about 180° F. for 2-3 hours.

In certain embodiments, a non-humic organic carbon source is used for preparing the semi-humic composition. It is contemplated that the organic acid can be any organic acid, such as ethylene diamine tetraacetic acid, hydroxyethylene diamine triacetic acid, diethylene triamine pentaacetic acid, nitrillo triacetic acid, ethanol diglycine, citric acid, galactaric acid, gluconic acid, glucono delta-lactone, glucoheptoic acid, glucaric acid, glutaric acid, glutamic acid, tartaric acid or tartronic acid. In certain embodiments, the composition further comprises gluconic acid. It is contemplated that the organic acid can be present in any amount, although it is contemplated that an amount of up to about 10% is effective. Therefore, in certain embodiments, the semi-humic composition comprises about 45-50% water by weight, about 15-20% of an aqueous base (e.g., a 50% KOH solution in water), about 20-25% of organic non-humic nitrogenous source, and about 5-20% of an organic acid.

The pH of the composition can vary due to the concentration of base employed in any of the processes described herein. In certain embodiments, the pH of the composition is about 10, or greater than about 10, or about 11, or about 12, or about 13, or about 14, or about 10-14, or about 11-12, or about 12-13, or about 13-14.

In any one embodiment, any composition as described herein can further comprise additional fertilizer. The fertilizer may comprise any nitrogen and/or phosphorus containing fertilizer used for agricultural or other plant growth enhancing purposes. The fertilizer as used herein can comprise one or more of a urea component, an ammonium component, a nitrate component, an ammonia component, an organic nitrogen component, and/or a phosphorus component. In certain embodiments, the fertilizer is an organic fertilizer.

In certain embodiments, the fertilizer and a semi-humic or aqueous composition as described herein are pre-mixed in solution prior to the addition to the soil. Their respective concentrations may range from 1% to about 20%, or from 1% to about 15%, or from 1% to about 10% by weight of any of the compositions described herein to fertilizer. In certain embodiments, the weight/weight ratio of any of the compositions described herein to fertilizer is about 1:100 to about 2:1. Exemplary ratios further include about 1:90; about 1:75; about 1:60; about 1:50; about 1:25; about 1:10; and about 1:1.

Methods

In one aspect, the present disclosure involves treating the soil of an agricultural, turf or sod grass field or other planting site with a semi-humic composition described herein, or obtained by the processes described herein, or an aqueous composition comprising the same.

In practice, organic residues may be added to the field following harvest. Decomposition of such residues and nitrogen release therefrom (mineralization) is seldom synchronized with crop growth. Use of the present method helps to promote nitrogen mineralization so that the nitrogen becomes available as a plant nutrient at a time that beneficially coincides with the crop's need for nitrogen for optimum growth.

The semi-humic composition described herein provides more mineralized Nitrogen (e.g., at about two weeks) when compared to blood meal granules at the same rate of Nitrogen. Provided herein is a method of increasing the amount of mineralized Nitrogen (e.g., nitrate) in soil by at least about 20% after up to about 2 weeks, comprising applying a semi-humic composition to soil. In certain embodiments, the semi-humic composition is applied to the soil at a concentration of at least about 10 mg of semi-humic composition per 100 grams of soil, or between about 10 mg and 1 gram of semi-humic composition per about 100 grams of soil. In certain embodiments, the amount of mineralized Nitrogen in the soil is increased by at least about 50%, or at least about 45%, or at least about 40%, or at least about 35%, or at least about 30%, or at least about 25%, or at least about 20% after about 2 weeks.

In addition, as shown by the Examples below, the standard deviations of measured mineralized soil Nitrogen at each time point from the semi-humic composition are almost an order of magnitude smaller than the blood meal granules treatment. This suggests that the semi-humic composition provides both a faster and, importantly, more consistent mineralized Nitrogen to meet plant demand.

Accordingly, provided herein is a method of increasing the rate of nitrogen mineralization in soil, comprising applying the semi-humic composition disclosed herein to soil. In certain embodiments, the rate of nitrogen mineralization in soil is increased by at least about 20%, or at least about 30%, or at least about 40%, or at least about 50%, or more, after about 1 week, or about 2 weeks, or about 3 weeks, or about 4 weeks, as compared to the rate of nitrogen mineralization from applying a standard organic non-humic nitrogenous source (e.g., blood meal, hydrolyzed soybean meal, hydrolyzed bovine serum isolate, etc.).

Also provided, in one embodiment, is a method for increasing nitrogen uptake within a crop, comprising applying a semi-humic composition to soil and/or to the crop. In certain embodiments, the weight of nitrogen contained in the biomass of the crop is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the weight of nitrogen contained in the biomass of a crop where a semi-humic composition was not applied. In certain embodiments, the weight of nitrogen contained in the biomass of the crop is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the weight of nitrogen contained in the biomass of a crop where an organic Nitrogen source was applied.

A further benefit to more of the Nitrogen applied to the soil and/or the crop being made available for uptake by the plant, is an increased Nitrogen content in the crop itself, which for example, can be measured as an increase in grain protein content, or feed value in hay. Therefore, in one embodiment, provided herein is a method of increasing nitrogen content in a crop comprising applying the semi-humic composition as disclosed herein to soil and/or to the crop. In certain embodiments, the weight of nitrogen contained in the biomass of the crop is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the weight of nitrogen contained in the biomass of a crop where a semi-humic composition was not applied. In certain embodiments, the weight of nitrogen contained in the biomass of the crop is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the weight of nitrogen contained in the biomass of a crop where an organic Nitrogen source was applied.

In addition, since more of the Nitrogen applied is made available for uptake by the plant, also provided herein is a method for limiting the risk of Nitrogen contamination of the environment that has previously accompanied the use of organic Nitrogen-based fertilizers. Subsurface nitrogen adsorption also minimizes accumulation of nitrates and ammonium in the surface soil, which can otherwise lead to denitrification and resultant volatilization of nitrogen gas or nitrous oxide from the soil or runoff with rainfall.

As shown in Example 5, the semi-humic composition described herein performed better that the organic Nitrogen source alone (e.g., blood meal alone) in various key plant growth parameters. Therefore, these results support the conclusion that the semi-humic composition described herein would be a superior source of Nitrogen that is able to be readily utilized by the crop for growth and development. In addition, the semi-humic composition described herein can be used by organic farmers.

Accordingly, in certain embodiments, provided is a method of enhancing crop growth comprising applying the semi-humic composition as described herein to soil and/or to the crop. In certain embodiments, the semi-humic composition as described herein which is derived from one or more organic Nitrogen sources, results in a comparable crop to that provided using urea, a nitrogen source commonly used in conventional farming systems. In certain embodiments, the crop growth is enhanced by at least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the crop growth where a semi-humic composition was not applied In certain embodiments, the crop growth is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the crop growth where an organic Nitrogen source was applied.

By increasing the crop growth and root size, it is further contemplated that the crop yield would be increased as well. In certain embodiments, provided is a method of increasing crop yield comprising applying the semi-humic composition as disclosed herein to soil and/or to the crop. In certain embodiments, the crop yield is enhanced by at least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the crop yield where a semi-humic composition was not applied. In certain embodiments, the crop yield is increased by least about 15%, or about 50%, or about 45%, or about 40%, or about 35%, or about 30%, or about 25%, or about 20%, or about 15%, or about 10%, or about 5% by weight versus the crop yield where an organic Nitrogen source was applied.

It is contemplated that the semi-humic composition disclosed herein is easier to apply, and can be used at lower application rates than many other sources of organic Nitrogen. Thus by using the semi-humic composition disclosed herein, the amount of Nitrogen applied can be decreased while still maintaining the benefits of the semi-humic composition. The amount of semi-humic composition to be applied may be calculated in a variety of ways. For example, the amount of the semi-humic composition may be expressed in a variety of units, including mass or volume of material per mass or volume of soil, area of land, or mass of fertilizer. In one embodiment, the rate may be calculated by the mass of the semi-humic composition per mass of soil or the estimated mass of nitrogen in the semi-humic composition. In certain embodiments, the semi-humic composition may be applied at a concentration of at least about 1 milligram, or 2 milligrams, or 5 milligrams or 10 milligrams or 20 milligrams of the semi-humic composition per 10 grams of soil. Alternative ratios for applying the semi-humic composition are described below. Suitable rates include:

Units Liters semi-humic Liter semi-humic composition composition per hectare per 100 kg Nitrogen Low end of 5 1,000 range 100, 500, 1,500, 3,000, 2,000, 3,000, 5,000, 10,000, 6,000, or 10,000 15,000 High end of 15,000 20,000 range

In other embodiments, the amount of semi-humic composition applied to the soil ranges from about 0.1 mL to about 10 mL of the semi-humic composition kilogram of soil, or about 5 mL of the semi-humic composition per kilogram of soil, or about 2 mL per kilogram of soil, or about 1 mL per kilogram of soil, or about 0.5 mL of the semi-humic composition per kilogram of soil, or about 0.3 mL of the semi-humic composition per kilogram of soil. In certain embodiments, the amount of the semi-humic composition applied to the soil ranges from about 0.001 mL to about 50 mL of the semi-humic composition per kilogram of soil. Typically, the semi-humic composition is applied to the soil in a range of from about 300 to about 15,000 Liters per hectare of land.

However, as the semi-humic composition can be applied to the soil or the crop during plant grown, the amount rate may vary and can be calculated based on area. In certain embodiments, the semi-humic composition is applied to the soil and/or to the crop at a concentration of less than about 10 pounds of Nitrogen per acre, or about 1 pound of Nitrogen per acre, or about 3 pounds of Nitrogen per acre, or about 5 pounds of Nitrogen per acre, or about 10 pounds of Nitrogen per acre, or about 25 pounds of Nitrogen per acre, or about 50 pounds of Nitrogen per acre, or about 75 pounds of Nitrogen per acre, or about 100 pounds of Nitrogen per acre, or about 150 pounds of Nitrogen per acre, or about 200 pounds of Nitrogen per acre, or about 250 pounds of Nitrogen per acre, or about 300 pounds of Nitrogen per acre, or greater than about 300 pounds of Nitrogen per acre.

The soil to be treated can be any soil type, including, but not limited to, clay, loam, clay-loam, silt-loam, and the like. However, it is contemplated that the soils to be treated with the semi-humic composition described herein can have any amount of organic matter (typically from less than 1% to greater than about 20%).

In one embodiment, the semi-humic composition is applied in combination with additional fertilizer, where the semi-humic composition and fertilizer are pre-mixed in solution prior to the addition to the soil. Their respective concentrations may range from 1% to about 20%, or from 1% to about 15%, or from 1% to about 10% by weight of the semi-humic composition to fertilizer. In certain embodiments, the weight/weight ratio of the semi-humic composition to fertilizer is from about 1:100 to about 2:1. Exemplary ratios further include about 1:90; about 1:75; about 1:60; about 1:50; about 1:25; about 1:10; and about 2:1.

Examples Example 1: Increase in Humic-Like Fraction of a Semi-Humic Composition

The process described herein, and as shown in FIGS. 1A and 1B, results in a liquid suspension, referred to herein as Composition 1, with an unexpected increase in the base extracted, acid precipitated fraction.

Methods

Extracts from leonardite and other humic substances are defined as humic acid, fulvic acid or humin based on the following operational definitions (see, e.g., Aiken, George R., et al. Humic substances in soil, sediment, and water: geochemistry, isolation and characterization. John Wiley & Sons, 1985):

1. Humic Acid: the base extracted, acid precipitated fraction

2. Fulvic Acid: the base extracted, acid soluble fraction

3. Humin: the base extracted, insoluble fraction

The CDFA Humic Acid Method is currently the widely accepted method for quantifying Humic Acid and is available to customers at some soil and fertilizer labs. The CDFA Method reports Humic Acid as a weight percentage of the initial sample. In this example all organic inputs and the final semi-humic composition were analyzed by the CDFA Method. The result of the CDFA Method on blood meal and the finished semi-humic composition are referred to as humic-like because these samples may contain all or some non-humified organic matter. An exemplary method for preparing a 1,000 pound batch of the semi-humic composition from leonardite and blood meal was as described below.

The following assumes a blood meal total nitrogen content of 14% for a target of 3% nitrogen by weight in the composition. A sufficient amount of water (e.g., 60.5% by weight of the total batch weight) was heated to at least about 160° F. Base (e.g., 50% KOH in Water) was then added (e.g., 9% by weight of the total batch weight) followed by blood meal (e.g., 23% of the batch weight) (Boer Blood Meal, manufactured by Boer Commodities, Inc.). The resulting composition was then agitated at a temperature of at least about 160° F. for at least about 2 hours at which time leonardite ore was added (e.g., 7.5% by weight of the total batch weight). The resulting composition was then agitated at a temperature of at least about 160° F. for an additional time (e.g., 1-2 hours), during which time, additional water was added to make up for evaporative loss. After the allotted time, the liquid portion was separated from any remaining solids (decanting and filtration through a 149 mesh filter to afford the semi-humic composition).

Results

Table 1 shows results of the CDFA Method for the blood meal and leonardite used to produce the semi-humic composition. This composition is also called Composition 1.

TABLE 1 Humic Acid and Humic-Like Content of Organic Inputs Input % Humic Acid % Humic-Like Blood — 0 Meal Leonardite 76.5 —

Table 2 shows the expected and actual Humic-Like content of the Semi-Humic composition. The expected Humic-Like content is calculated based on the assumption that 100% of the Humic Acid in leonardite was extracted and included in the final Semi-Humic Composition.

TABLE 2 Expected vs Actual Humic-Like Content of Semi-Humic Composition Semi-Humic Composition Semi-Humic Composition Prepared via FIG. 1A Prepared via FIG. 1B Expected % Expected % Humic-Like Actual Humic- Humic-Like Actual Humic- Content Like Content Content Like Content 5.10% 16.18 3.90% 14.14 5.10% 14.94 3.90% 12.65 5.10% 14.3 5.10% 15.18 5.10% 18.13 5.10% 10.1 Standard 1.34 Standard Deviation 0.75 Deviation

Conclusion

The actual Humic-Like content of the Semi-Humic Composition prepared as described herein (see, e.g., FIGS. 1A and 1B) is, at least, nearly twice as large as the expected value, which assumes 100% organic extraction of leonardite. However, as shown above in Table 2, the actual Humic-Like content of the Semi-Humic Compositions prepared via the methods described herein are more than twice, or even more than three times larger than the expected value (i.e., 2.8-3.6 times larger than the expected value). This suggests that the processes in FIGS. 1A and 1B result in chemical interactions between non-humified blood meal-derived organic matter and humified leonardite-derived organic matter, resulting in a Semi-Humic Composition.

Example 2: Molecular Characterization of the Semi-Humic Composition, a Blood Meal Solution and a Standard Humic Extract

Fourier Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) is a powerful tool for the molecular characterization of complex organic mixtures. The ultra-high mass resolution and mass accuracy of FTICR-MS allows for the identification of elemental compositions for thousands of species, with minimal sample preparation. For singly charged ions of <700 Da, unambiguous molecular formulas can be assigned directly from the measured mass if about 1 ppm mass accuracy can be achieved.′ In this example the semi-humic composition, a blood meal solution and a standard humic extract were characterized with FTICR-MS.

Methods

Sample Preparation.

The semi-humic composition was prepared as previously described. The standard humic extract was prepared by combining 172 g of dry leonardite, 731 g of water and 97 g of 50% (w/w) KOH solution. After mixing for 3 hours, the insoluble residue was removed and the supernatant was isolated. The blood meal solution was prepared by combining 250 g of blood meal granules, 650 g of water and 94 g of 50% (w/w) KOH solution. The mixture was then mixed for 1.5 hours at 160° F. The resulting liquid contained 3.7% (w/w) nitrogen.

Analytical Method.

Analysis was performed by LC-ESI-MS on a 7T Solarix FTICR-MS (Bruker) equipped with an Infinity Cell (Bruker) and a Surveyor Plus HPLC System (Thermo). Each sample was diluted 200 fold by volume and run in ESI negative mode. ESI Source Conditions and LC Method Details are shown in Tables 3 and 4.

TABLE 3 ESI Negative Source Conditions End Capillary Plate Nebulizer Dry Gas Dry FID Voltage Offset Pressure Flow Temp Transient Polarity (V) (V) (bar) (L/min) (° C.) (s) ESI 4500 −500 3 3 200 0.4893 Negative

TABLE 4 LC Method Details Total Sample Flow Method Injection Rate LC Method Time Column Solvent A Solvent B Volume (mL/min) Description (min) Merck ZIC- Acetonitrile Water 5 μL 0.25-0.9 Ramp: 50 pHILIC [95% A-5% B], 150 * 4.6 mm, [5% A-95% B] 5 μm Equilibrate: [95% A-5% B]

Data Analysis.

Post-acquisition, spectra were externally calibrated against a known standardized tuning mixture. Mass lists including peaks above a SN threshold of three, relative intensity threshold of 0.01% and absolute intensity threshold of 0.5 were then generated. Only masses in the 120-700 m/z range were used to determine molecular formulas since mass accuracy is highest in the lower mass range for FTICR-MS. To generate molecular formulas, the maximum error allowed between the measured and theoretical m/z from the calculated molecular formula was set to 1.0 ppm. Deprotonated (M-H) ions were included in formula determination and all final mass lists used for subsequent analysis were converted to their Neutral Sum equivalent. Molecular formulas were then screened to exclude 0/C>1.5 and N/C>0.7 as well as include H/C<2.25 and H/C>0.33. These cutoffs were similar to those determined for natural organic matter by Stubbins, et al. (2010).²

Results

Table 5A displays the number of molecular formula assigned to each sample. The semi-humic composition has more assigned molecular formulas compared to the standard humic extract or blood meal solution. FIG. 2 displays a Venn Diagram that shows the number of overlapping and unique molecular formulas assigned to each sample. Only 61 out of the 5152 total molecular formulas identified are consistently shared amongst all samples. In addition, 1507 out of the 2004 molecular formulas identified in the semi-humic composition are unique. Table 5B displays those formulas in their neutral sum format.

TABLE 5A Number of Molecular Formulas Attributed to Each Sample Type Sample Number of Molecular Formulas (120-700 m/z) Semi-Humic 2004 Composition Standard Humic 1702 Extract Blood Meal Solution 1446

TABLE 5B Unique Molecular Formulas Identified in the Semi-Humic Composition Unique Formulas H/C O/C N/C C₁₀H₇N₇O₇S 0.70 0.70 0.70 C₉H₆O₆ 0.67 0.67 0.00 C₇H₆O₅S 0.86 0.71 0.00 C₇H₅NO₆ 0.71 0.86 0.14 C₁₂H₈N₂O₉S₉ 0.67 0.75 0.17 C₁₅H₁₀N₄O₉S 0.67 0.60 0.27 C₇H₆N₂O₆ 0.86 0.86 0.29 C₆H₄N₂O₅S₃ 0.67 0.83 0.33 C₁₈H₁₂N₁₂S 0.67 0.00 0.67 C₄₆H₂₈ 0.61 0.00 0.00 C₂₇H₂₀S 0.74 0.00 0.00 C₄₀H₃₀ 0.75 0.00 0.00 C₃₇H₃₀ 0.81 0.00 0.00 C₃₈H₃₂ 0.84 0.00 0.00 C₄₀H₃₄ 0.85 0.00 0.00 C₂₈H₂₄S₄ 0.86 0.00 0.00 C₃₉H₃₄ 0.87 0.00 0.00 C₂₇H₂₄S₄ 0.89 0.00 0.00 C₂₉H₂₆S 0.90 0.00 0.00 C₄₀H₃₆ 0.90 0.00 0.00 C₂₆H₂₄S₄ 0.92 0.00 0.00 C₂₈H₂₆S₄ 0.93 0.00 0.00 C₁₇H₁₆S₂ 0.94 0.00 0.00 C₂₅H₂₄S₄ 0.96 0.00 0.00 C₂₇H₂₆S₄ 0.96 0.00 0.00 C₂₉H₂₈S 0.97 0.00 0.00 C₄₂H₃₇N 0.88 0.00 0.02 C₄₉H₄₃NS 0.88 0.00 0.02 C₄₃H₃₉N 0.91 0.00 0.02 C₄₃H₄₁N 0.95 0.00 0.02 C₂₉H₂₁NS 0.72 0.00 0.03 C₃₂H₂₇NS 0.84 0.00 0.03 C₃₄H₂₉NS 0.85 0.00 0.03 C₂₄H₁₉NS 0.79 0.00 0.04 C₄₆H₃₈N₂ 0.83 0.00 0.04 C₅₀H₄₂N₂ 0.84 0.00 0.04 C₂₄H₂₁NS 0.88 0.00 0.04 C₄₆H₄₂N₂ 0.91 0.00 0.04 C₂₇H₂₅NS 0.93 0.00 0.04 C₄₅H₄₄N₂ 0.98 0.00 0.04 C₄₂H₃₈N₂ 0.90 0.00 0.05 C₄₄H₄₀N₂ 0.91 0.00 0.05 C₁₆H₁₁NS₂ 0.69 0.00 0.06 C₁₈H₁₃NS₂ 0.72 0.00 0.06 C₃₃H₂₈N₂S 0.85 0.00 0.06 C₁₇H₁₅NS₂ 0.88 0.00 0.06 C₂₉H₂₈N₂S 0.97 0.00 0.07 C₃₃H₃₁N₃S 0.94 0.00 0.09 C₃₀H₂₅N₃S 0.83 0.00 0.10 C₄₆H₃₇N₅ 0.80 0.00 0.11 C₃₇H₃₂N₄S 0.86 0.00 0.11 C₄₆H₄₅N₅S 0.98 0.00 0.11 C₂₄H₁₇N₃ 0.71 0.00 0.13 C₂₉H₂₆N₄S₂ 0.90 0.00 0.14 C₂₀H₁₃N₃S 0.65 0.00 0.15 C₂₆H₂₄N₄S₂ 0.92 0.00 0.15 C₄₄H₃₇N₇S 0.84 0.00 0.16 C₂₃H₁₆N₄ 0.70 0.00 0.17 C₃₃H₃₂N₆S 0.97 0.00 0.18 C₂₂H₂₁N₅ 0.95 0.00 0.23 C₁₆H₁₂N₄ 0.75 0.00 0.25 C₁₆H₁₄N₄S₃ 0.88 0.00 0.25 C₁₈H₁₅N₅S 0.83 0.00 0.28 C₂₄H₂₁N₇ 0.88 0.00 0.29 C₂₄H₂₂N₈ 0.92 0.00 0.33 C₃₃H₃₂N₁₂ 0.97 0.00 0.36 C₁₉H₁₂N₈S 0.63 0.00 0.42 C₁₈H₁₆N₈S 0.89 0.00 0.44 C₂₇H₂₆N₁₂ 0.96 0.00 0.44 C₂₉H₂₀N₁₆ 0.69 0.00 0.55 C₁₉H₁₃N₁₁ 0.68 0.00 0.58 C₄₇H₃₀OS₂ 0.64 0.02 0.00 C₄₆H₃₀OS₂ 0.65 0.02 0.00 C₄₅H₃₄O 0.76 0.02 0.00 C₅₂H₅₀O 0.96 0.02 0.00 C₄₃H₃₁NO 0.72 0.02 0.02 C₄₄H₃₃NO 0.75 0.02 0.02 C₄₁H₃₃NO 0.80 0.02 0.02 C₄₁H₃₇NO 0.90 0.02 0.02 C₄₈H₃₈N₂O 0.79 0.02 0.04 C₄₆H₃₈N₂O 0.83 0.02 0.04 C₄₅H₄₂N₂O 0.93 0.02 0.04 C₄₄H₄₀N₂O 0.91 0.02 0.05 C₄₄H₂₉N₃OS₂ 0.66 0.02 0.07 C₄₃H₃₃N₇O 0.77 0.02 0.16 C₄₂H₄₁N₇OS 0.98 0.02 0.17 C₄₀H₃₂O 0.80 0.03 0.00 C₃₁H₃₀OS 0.97 0.03 0.00 C₃₀H₂₁NOS 0.70 0.03 0.03 C₃₉H₂₉NOS₅ 0.74 0.03 0.03 C₂₉H₂₃NOS 0.79 0.03 0.03 C₃₃H₂₇NOS 0.82 0.03 0.03 C₄₀H₃₅NO 0.88 0.03 0.03 C₃₀H₂₇NOS 0.90 0.03 0.03 C₂₉H₂₇NOS 0.93 0.03 0.03 C₃₀H₂₉NOS 0.97 0.03 0.03 C₃₁H₂₄N₂OS 0.77 0.03 0.06 C₂₉H₂₈N₂OS 0.97 0.03 0.07 C₃₁H₂₉N₃O 0.94 0.03 0.10 C₃₀H₂₂N₄OS₂ 0.73 0.03 0.13 C₂₉H₂₃N₁₅OS₂ 0.79 0.03 0.52 C₂₄H₂₀OS₄ 0.83 0.04 0.00 C₂₆H₂₂OS₄ 0.85 0.04 0.00 C₂₄H₂₂OS 0.92 0.04 0.00 C₂₃H₂₂OS₂ 0.96 0.04 0.00 C₂₇H₂₆OS₄ 0.96 0.04 0.00 C₄₆H₄₃NO₂ 0.93 0.04 0.02 C₅₀H₄₀N₂O₂ 0.80 0.04 0.04 C₂₈H₂₃NOS 0.82 0.04 0.04 C₂₈H₂₅NOS 0.89 0.04 0.04 C₂₅H₂₃NOS₄ 0.92 0.04 0.04 C₄₅H₄₂N₂O₂S 0.93 0.04 0.04 C₂₈H₂₇NOS 0.96 0.04 0.04 C₂₈H₂₆N₂OS 0.93 0.04 0.07 C₂₃H₁₇N₃O 0.74 0.04 0.13 C₂₆H₂₁N₅O 0.81 0.04 0.19 C₂₇H₂₀N₈O 0.74 0.04 0.30 C₂₁H₁₆OS₂ 0.76 0.05 0.00 C₄₄H₃₄O₂ 0.77 0.05 0.00 C₄₁H₃₂O₂S₃ 0.78 0.05 0.00 C₂₁H₁₈OS₂ 0.86 0.05 0.00 C₂₀H₁₈O 0.90 0.05 0.00 C₁₉H₁₈O 0.95 0.05 0.00 C₂₁H₂₀O 0.95 0.05 0.00 C₄₂H₄₀O₂ 0.95 0.05 0.00 C₄₂H₃₅NO₂ 0.83 0.05 0.02 C₄₁H₃₅NO₂ 0.85 0.05 0.02 C₄₄H₃₉NO₂ 0.89 0.05 0.02 C₄₄H₄₁NO₂ 0.93 0.05 0.02 C₁₉H₁₅NOS₂ 0.79 0.05 0.05 C₂₁H₁₇NOS₂ 0.81 0.05 0.05 C₁₉H₁₇NOS₂ 0.89 0.05 0.05 C₄₂H₃₅N₃O₂ 0.83 0.05 0.07 C₃₇H₃₅N₃O₂S 0.95 0.05 0.08 C₃₉H₂₆N₆O₂S 0.67 0.05 0.15 C₄₃H₃₉N₇O₂ 0.91 0.05 0.16 C₁₉H₁₈N₄O 0.95 0.05 0.21 C₂₀H₁₉N₁₁OS 0.95 0.05 0.55 C₁₇H₁₂O 0.71 0.06 0.00 C₁₇H₁₄OS₂ 0.82 0.06 0.00 C₁₈H₁₆OS₂ 0.89 0.06 0.00 C₄₈H₄₁NO₃ 0.85 0.06 0.02 C₁₈H₁₃NOS₂ 0.72 0.06 0.06 C₁₇H₁₃NOS₂ 0.76 0.06 0.06 C₁₈H₁₅NOS₂ 0.83 0.06 0.06 C₃₁H₂₆N₂O₂S 0.84 0.06 0.06 C₁₇H₁₅NOS₂ 0.88 0.06 0.06 C₁₈H₁₇NOS₂ 0.94 0.06 0.06 C₁₈H₁₄N₂OS₂ 0.78 0.06 0.11 C₃₄H₂₉N₇O₂ 0.85 0.06 0.21 C₁₇H₁₄N₄O 0.82 0.06 0.24 C₃₄H₃₂N₁₂O₂ 0.94 0.06 0.35 C₃₅H₃₃N₁₃O₂ 0.94 0.06 0.37 C₃₂H₂₈N₁₂O₂ 0.88 0.06 0.38 C₃₂H₃₀N₁₄O₂ 0.94 0.06 0.44 C₁₇H₁₅N₉OS₂ 0.88 0.06 0.53 C₁₄H₁₀OS₃ 0.71 0.07 0.00 C₁₄H₁₂OS₃ 0.86 0.07 0.00 C₃₀H₂₈O₂S 0.93 0.07 0.00 C₂₉H₂₅NO₂S 0.86 0.07 0.03 C₄₆H₄₂N₂O₃ 0.91 0.07 0.04 C₁₄H₁₁NOS₂ 0.79 0.07 0.07 C₁₄H₁₃NOS₃ 0.93 0.07 0.07 C₂₉H₁₈N₄O₂S₂ 0.62 0.07 0.14 C₂₈H₂₆N₄O₂S₂ 0.93 0.07 0.14 C₁₄H₉N₃OS 0.64 0.07 0.21 C₂₈H₂₀N₈O₂ 0.71 0.07 0.29 C₃₀H₂₉N₁₃O₂ 0.97 0.07 0.43 C₂₅H₂₀O₂S₂ 0.80 0.08 0.00 C₂₄H₂₀O₂S₂ 0.83 0.08 0.00 C₂₄H₂₂O₂S₂ 0.92 0.08 0.00 C₄₈H₃₉NO₄ 0.81 0.08 0.02 C₁₃H₁₂N₂OS₇ 0.92 0.08 0.15 C₂₄H₂₃N₇O₂ 0.96 0.08 0.29 C₃₆H₂₉N₁₁O₃ 0.81 0.08 0.31 C₃₇H₃₀N₁₂O₃ 0.81 0.08 0.32 C₂₂H₁₄O₂S₂ 0.64 0.09 0.00 C₂₂H₁₆O₂S₂ 0.73 0.09 0.00 C₂₃H₁₈O₂S₂ 0.78 0.09 0.00 C₂₂H₁₈O₂S₂ 0.82 0.09 0.00 C₂₂H₂₀O₂S₂ 0.91 0.09 0.00 C₃₂H₃₁NO₃S 0.97 0.09 0.03 C₂₃H₁₅NO₂S₂ 0.65 0.09 0.04 C₂₃H₁₉NO₂ 0.83 0.09 0.04 C₂₃H₂₁N₇O₂ 0.91 0.09 0.30 C₂₃H₂₂N₈O₂ 0.96 0.09 0.35 C₂₀H₁₄O₂S₂ 0.70 0.10 0.00 C₂₁H₁₆O₂S₄ 0.76 0.10 0.00 C₂₁H₁₆O₂S₂ 0.76 0.10 0.00 C₂₀H₁₆O₂S₂ 0.80 0.10 0.00 C₂₁H₂₀O₂S₂ 0.95 0.10 0.00 C₄₂H₃₃NO₄ 0.79 0.10 0.02 C₃₁H₂₉NO₃S 0.94 0.10 0.03 C₂₀H₁₅NO₂S₂ 0.75 0.10 0.05 C₂₀H₁₇NO₂S₂ 0.85 0.10 0.05 C₂₀H₁₉NO₂S₂ 0.95 0.10 0.05 C₂₁H₁₈N₄O₂ 0.86 0.10 0.19 C₂₀H₁₄N₄O₂ 0.70 0.10 0.20 C₃₁H₂₀N₈O₃ 0.65 0.10 0.26 C₂₁H₁₈N₆O₂S₃ 0.86 0.10 0.29 C₂₀H₁₇N₇O₂ 0.85 0.10 0.35 C₁₈H₁₂O₂ 0.67 0.11 0.00 C₁₈H₁₂O₂S₃ 0.67 0.11 0.00 C₁₈H₁₂O₂S₂ 0.67 0.11 0.00 C₁₉H₁₄O₂S₂ 0.74 0.11 0.00 C₁₈H₁₄O₂S₂ 0.78 0.11 0.00 C₁₈H₁₆O₂S₂ 0.89 0.11 0.00 C₁₉H₁₈O₂S₂ 0.95 0.11 0.00 C₁₉H₁₇NO₂S₂ 0.89 0.11 0.05 C₁₈H₁₃NO₂S₂ 0.72 0.11 0.06 C₁₈H₁₅NO₂S₂ 0.83 0.11 0.06 C₁₈H₁₇NO₂S₂ 0.94 0.11 0.06 C₂₇H₂₁N₅O₃ 0.78 0.11 0.19 C₁₈H₁₄N₆O₂ 0.78 0.11 0.33 C₁₈H₁₅N₇O₂ 0.83 0.11 0.39 C₁₉H₁₈N₈O₂S₂ 0.95 0.11 0.42 C₂₅H₁₈O₃S₂ 0.72 0.12 0.00 C₁₇H₁₅NO₂S₂ 0.88 0.12 0.06 C₂₆H₂₂N₈O₃ 0.85 0.12 0.31 C₂₆H₂₄N₈O₃ 0.92 0.12 0.31 C₂₄H₁₆O₃S₂ 0.67 0.13 0.00 C₂₃H₁₆O₃S₂ 0.70 0.13 0.00 C₁₆H₁₂O₂S₃ 0.75 0.13 0.00 C₁₆H₁₂O₂S₂ 0.75 0.13 0.00 C₁₅H₁₂O₂S₃ 0.80 0.13 0.00 C₂₄H₂₀O₃S₂ 0.83 0.13 0.00 C₂₃H₂₀O₃S₂ 0.87 0.13 0.00 C₁₆H₁₄O₂S₂ 0.88 0.13 0.00 C₂₃H₂₂O₃S₂ 0.96 0.13 0.00 C₄₀H₂₆N₂O₅ 0.65 0.13 0.05 C₁₆H₁₃NO₂S₂ 0.81 0.13 0.06 C₁₆H₁₅NO₂S₂ 0.94 0.13 0.06 C₂₄H₁₈N₄O₃ 0.75 0.13 0.17 C₂₂H₁₄O₃S₂ 0.64 0.14 0.00 C₂₂H₁₆O₃S₂ 0.73 0.14 0.00 C₂₂H₁₈O₃S₂ 0.82 0.14 0.00 C₁₄H₁₂O₂S₂ 0.86 0.14 0.00 C₂₂H₂₀O₃S₂ 0.91 0.14 0.00 C₂₁H₁₃NO₃S₂ 0.62 0.14 0.05 C₂₂H₁₅NO₃S₂ 0.68 0.14 0.05 C₂₁H₁₅NO₃S₂ 0.71 0.14 0.05 C₂₂H₁₇NO₃S₂ 0.77 0.14 0.05 C₂₁H₁₇NO₃S₂ 0.81 0.14 0.05 C₂₂H₁₉NO₃S₂ 0.86 0.14 0.05 C₂₂H₂₁NO₃S₂ 0.95 0.14 0.05 C₂₁H₁₄N₄O₃ 0.67 0.14 0.19 C₂₈H₂₀N₁₄O₄ 0.71 0.14 0.50 C₂₀H₁₄O₃S₂ 0.70 0.15 0.00 C₂₀H₁₆O₃S₁₀ 0.80 0.15 0.00 C₂₀H₁₄N₄O₃ 0.70 0.15 0.20 C₂₀H₁₅N₅O₃S₁₀ 0.75 0.15 0.25 C₂₀H₁₇N₅O₃ 0.85 0.15 0.25 C₁₃H₉N₇O₂S₁₀ 0.69 0.15 0.54 C₂₀H₁₃N₁₁O₃S 0.65 0.15 0.55 C₁₉H₁₄O₃S₂ 0.74 0.16 0.00 C₂₅H₂₀N₄O₄ 0.80 0.16 0.16 C₁₉H₁₈N₆O₃S₃ 0.95 0.16 0.32 C₂₃H₁₆O₄S₂ 0.70 0.17 0.00 C₂₃H₁₈O₄S₂ 0.78 0.17 0.00 C₁₈H₁₄O₃S₂ 0.78 0.17 0.00 C₁₈H₁₆O₃S₂ 0.89 0.17 0.00 C₁₈H₁₅NO₃S₂ 0.83 0.17 0.06 C₂₃H₁₆N₄O₄ 0.70 0.17 0.17 C₁₇H₁₂O₃S₂ 0.71 0.18 0.00 C₁₇H₁₄O₃S₂ 0.82 0.18 0.00 C₁₇H₁₁NO₃S₂ 0.65 0.18 0.06 C₁₇H₁₃NO₃S₂ 0.76 0.18 0.06 C₁₇H₁₅NO₃S₂ 0.88 0.18 0.06 C₂₂H₁₆N₄O₄ 0.73 0.18 0.18 C₂₂H₁₈N₄O₄ 0.82 0.18 0.18 C₂₁H₁₆O₄S₂ 0.76 0.19 0.00 C₁₆H₁₄O₃S₂ 0.88 0.19 0.00 C₂₁H₁₅NO₄S₂ 0.71 0.19 0.05 C₂₁H₁₉NO₄S₂ 0.90 0.19 0.05 C₁₆H₁₅NO₃S₂ 0.94 0.19 0.06 C₂₇H₂₆N₄O₅ 0.96 0.19 0.15 C₁₀H₆O₂S₅ 0.60 0.20 0.00 C₂₀H₁₄O₄S₂ 0.70 0.20 0.00 C₁₅H₁₂O₃S₂ 0.80 0.20 0.00 C₁₅H₁₄O₃S₂ 0.93 0.20 0.00 C₂₀H₁₃NO₄S₂ 0.65 0.20 0.05 C₂₀H₁₅NO₄S₂ 0.75 0.20 0.05 C₂₀H₁₉NO₄S₂ 0.95 0.20 0.05 C₁₅H₁₁NO₃S₂ 0.73 0.20 0.07 C₂₅H₁₆N₄O₅ 0.64 0.20 0.16 C₂₀H₁₈N₁₀O₄S 0.90 0.20 0.50 C₁₄H₁₂O₃S₃ 0.86 0.21 0.00 C₁₉H₁₃NO₄S₂ 0.68 0.21 0.05 C₁₉H₁₅NO₄S₂ 0.79 0.21 0.05 C₁₄H₉NO₃ 0.64 0.21 0.07 C₁₄H₁₃NO₃S₂ 0.93 0.21 0.07 C₂₄H₂₂N₄O₅ 0.92 0.21 0.17 C₃₆H₃₀N₂O₈ 0.83 0.22 0.06 C₂₃H₁₄N₂O₅S₉ 0.61 0.22 0.09 C₂₃H₁₆N₄O₅ 0.70 0.22 0.17 C₁₈H₁₄N₆O₄S₃ 0.78 0.22 0.33 C₂₂H₁₉NO₅S₂ 0.86 0.23 0.05 C₁₃H₁₁NO₃S₂ 0.85 0.23 0.08 C₂₂H₁₄N₄O₅ 0.64 0.23 0.18 C₂₂H₁₄N₁₀O₅S 0.64 0.23 0.45 C₂₂H₁₆N₁₀O₅S 0.73 0.23 0.45 C₁₇H₁₂O₄S₂ 0.71 0.24 0.00 C₂₁H₁₆O₅S₂ 0.76 0.24 0.00 C₁₇H₁₄O₄S₂ 0.82 0.24 0.00 C₁₇H₁₁NO₄S₂ 0.65 0.24 0.06 C₁₇H₁₆N₆O₄S₃ 0.94 0.24 0.35 C₂₁H₂₀N₁₀O₅S 0.95 0.24 0.48 C₂₀H₁₄O₅S₈ 0.70 0.25 0.00 C₁₆H₁₂O₄S₂ 0.75 0.25 0.00 C₂₀H₁₃NO₅S₂ 0.65 0.25 0.05 C₁₆H₁₃NO₄S₂ 0.81 0.25 0.06 C₁₉H₁₅NO₅S₂ 0.79 0.26 0.05 C₂₃H₁₄N₄O₆ 0.61 0.26 0.17 C₃₁H₂₂N₆O₈S₂ 0.71 0.26 0.19 C₁₉H₁₈N₄O₅ 0.95 0.26 0.21 C₂₃H₁₄N₁₀O₆S 0.61 0.26 0.43 C₁₁H₁₀O₃ 0.91 0.27 0.00 C₁₅H₁₄O₄S₂ 0.93 0.27 0.00 C₁₅H₁₃NO₄S₂ 0.87 0.27 0.07 C₁₁H₉NO₃ 0.82 0.27 0.09 C₂₂H₂₀N₄O₆ 0.91 0.27 0.18 C₁₈H₁₁N₅O₅ 0.61 0.28 0.28 C₁₈H₁₃N₅O₅S₉ 0.72 0.28 0.28 C₁₄H₁₂O₄S₂ 0.86 0.29 0.00 C₂₁H₁₄N₄O₆ 0.67 0.29 0.19 C₁₀H₈O₃ 0.80 0.30 0.00 C₂₀H₁₂N₄O₆ 0.60 0.30 0.20 C₂₀H₁₈N₄O₆ 0.90 0.30 0.20 C₂₀H₁₈N₁₀O₆S 0.90 0.30 0.50 C₁₃H₁₀O₄S₂ 0.77 0.31 0.00 C₁₃H₁₁NO₄S₂ 0.85 0.31 0.08 C₁₆H₁₄N₄O₅ 0.88 0.31 0.25 C₁₉H₁₂O₆S₂ 0.63 0.32 0.00 C₃₁H₂₈N₄O₁₀ 0.90 0.32 0.13 C₂₂H₁₄N₄O₇ 0.64 0.32 0.18 C₁₉H₁₆N₄O₆ 0.84 0.32 0.21 C₁₉H₁₆N₁₀O₆S 0.84 0.32 0.53 C₂₁H₁₆O₇S₉ 0.76 0.33 0.00 C₉H₈O₃ 0.89 0.33 0.00 C₁₈H₁₆N₄O₆ 0.89 0.33 0.22 C₃₄H₃₀N₂O₁₂ 0.88 0.35 0.06 C₁₁H₈O₄S₆ 0.73 0.36 0.00 C₁₁H₉NO₄S₆ 0.82 0.36 0.09 C₈H₅N₅O₃S₁₀ 0.63 0.38 0.63 C₁₃H₉N₇O₅S 0.69 0.38 0.54 C₁₃H₁₁N₇O₅S 0.85 0.38 0.54 C₁₀H₈O₄ 0.80 0.40 0.00 C₁₀H₇NO₄S₄ 0.70 0.40 0.10 C₁₃H₁₂N₆O₆S 0.92 0.46 0.46 C₈H₇NO₄S 0.88 0.50 0.13 C₁₂H₉N₇O₆S 0.75 0.50 0.58 C₁₃H₈N₆O₇S 0.62 0.54 0.46 C₉H₈N₆O₅S 0.89 0.56 0.67 C₉H₈O₅ 0.89 0.56 0.00 C₁₁H₈O₁₂S₄ 0.73 1.09 0.00 C₁₀H₆O₁₁S₂ 0.60 1.10 0.00 C₁₂H₉N₃O₁₄S₇ 0.75 1.17 0.25 C₁₅H₂₄S₂ 1.60 0.00 0.00 C₂₀H₃₂S₂ 1.60 0.00 0.00 C₂₅H₄₀S₄ 1.60 0.00 0.00 C₄₀H₆₄ 1.60 0.00 0.00 C₂₀H₃₂OS₂ 1.60 0.05 0.00 C₂₀H₃₂N₄OS₂ 1.60 0.05 0.20 C₁₅H₂₄OS₂ 1.60 0.07 0.00 C₁₅H₂₄O₂S₂ 1.60 0.13 0.00 C₃₅H₅₆O₇ 1.60 0.20 0.00 C₁₅H₂₄O₃S₂ 1.60 0.20 0.00 C₂₅H₄₀N₄O₅S₃ 1.60 0.20 0.16 C₁₀H₁₆O₃S₈ 1.60 0.30 0.00 C₁₅H₂₄O₅ 1.60 0.33 0.00 C₂₅H₄₀N₄O₁₀ 1.60 0.40 0.16 C₁₅H₂₄N₂O₂₀ 1.60 1.33 0.13 C₃₁H₅₀N₁₀S₂ 1.61 0.00 0.32 C₁₈H₂₉N₃OS₂ 1.61 0.06 0.17 C₂₈H₄₅NO₆S₂ 1.61 0.21 0.04 C₃₃H₅₃NO₁₀ 1.61 0.30 0.03 C₂₁H₃₄S₄ 1.62 0.00 0.00 C₂₁H₃₄N₂S₇ 1.62 0.00 0.10 C₃₉H₆₃N₅S₃ 1.62 0.00 0.13 C₂₉H₄₇N₃OS₄ 1.62 0.03 0.10 C₁₃H₂₁NOS₂ 1.62 0.08 0.08 C₂₆H₄₂N₈O₂ 1.62 0.08 0.31 C₃₄H₅₅NO₁₀ 1.62 0.29 0.03 C₃₄H₅₅NO₁₁ 1.62 0.32 0.03 C₂₉H₄₇NO₁₁S₂ 1.62 0.38 0.03 C₈H₁₃NO₆S₇ 1.63 0.75 0.13 C₁₉H₃₁N₃S₂ 1.63 0.00 0.16 C₃₀H₄₉N₅OS₄ 1.63 0.03 0.17 C₃₈H₆₂O₂S₄ 1.63 0.05 0.00 C₁₆H₂₆OS₂ 1.63 0.06 0.00 C₂₇H₄₄N₄O₂S₂ 1.63 0.07 0.15 C₁₆H₂₆O₂S₂ 1.63 0.13 0.00 C₂₄H₃₉N₃O₄S₂ 1.63 0.17 0.13 C₃₀H₄₉N₉O₅S 1.63 0.17 0.30 C₁₆H₂₆O₃S₂ 1.63 0.19 0.00 C₃₅H₅₇NO₇S₂ 1.63 0.20 0.03 C₃₀H₄₉N₇O₉S 1.63 0.30 0.23 C₁₆H₂₆O₉ 1.63 0.56 0.00 C₂₈H₄₆N₁₀S₂ 1.64 0.00 0.36 C₂₈H₄₆N₄O 1.64 0.04 0.14 C₂₂H₃₆N₁₄OS₃ 1.64 0.05 0.64 C₁₄H₂₃NOS₂ 1.64 0.07 0.07 C₂₂H₃₆N₁₄O₄S 1.64 0.18 0.64 C₂₂H₃₆N₄O₅S₂ 1.64 0.23 0.18 C₁₄H₂₃N₅O₅ 1.64 0.36 0.36 C₂₅H₄₁N₁₁O₉S 1.64 0.36 0.44 C₃₃H₅₄O₁₃ 1.64 0.39 0.00 C₁₁H₁₈O₁₄ 1.64 1.27 0.00 C₁₇H₂₈N₆S₃ 1.65 0.00 0.35 C₁₇H₂₈OS₂ 1.65 0.06 0.00 C₄₀H₆₆O₄S₂ 1.65 0.10 0.00 C₁₇H₂₈O₂S₂ 1.65 0.12 0.00 C₁₇H₂₈N₂O₂S₂ 1.65 0.12 0.12 C₂₃H₃₈N₆O₃S₂ 1.65 0.13 0.26 C₂₀H₃₃NO₆S 1.65 0.30 0.05 C₂₀H₃₃N₃O₆S₂ 1.65 0.30 0.15 C₂₃H₃₈N₂O₁₀S 1.65 0.43 0.09 C₁₇H₂₈N₂O₉ 1.65 0.53 0.12 C₂₉H₄₈N₄O 1.66 0.03 0.14 C₂₉H₄₈N₄O₄S₃ 1.66 0.14 0.14 C₃₂H₅₃NO₅S₃ 1.66 0.16 0.03 C₂₉H₄₈O₈ 1.66 0.28 0.00 C₁₈H₃₀N₂S₇ 1.67 0.00 0.11 C₂₄H₄₀N₁₄S₃ 1.67 0.00 0.58 C₃₉H₆₅NOS₄ 1.67 0.03 0.03 C₁₈H₃₀N₆OS₃ 1.67 0.06 0.33 C₂₇H₄₅NO₂S₄ 1.67 0.07 0.04 C₁₅H₂₅NOS₂ 1.67 0.07 0.07 C₂₇H₄₅N₅O₂S₂ 1.67 0.07 0.19 C₂₁H₃₅N₉O₂S₃ 1.67 0.10 0.43 C₃₀H₅₀N₂O₄S₂ 1.67 0.13 0.07 C₂₇H₄₅NO₆S₃ 1.67 0.22 0.04 C₁₅H₂₅NO₄S₂ 1.67 0.27 0.07 C₃₃H₅₅NO₁₀S₂ 1.67 0.30 0.03 C₂₄H₄₀O₁₁S 1.67 0.46 0.00 C₁₉H₃₂N₂S₇ 1.68 0.00 0.11 C₁₉H₃₂OS₂ 1.68 0.05 0.00 C₁₉H₃₂N₄OS₂ 1.68 0.05 0.21 C₁₉H₃₂N₄O₄S₂ 1.68 0.21 0.21 C₂₆H₄₄N₄O 1.69 0.04 0.15 C₂₆H₄₄N₁₀OS 1.69 0.04 0.38 C₁₆H₂₇N₃OS₂ 1.69 0.06 0.19 C₃₆H₆₁NO₆S₂ 1.69 0.17 0.03 C₁₃H₂₂O₃S₂ 1.69 0.23 0.00 C₁₃H₂₂N₂O₃S₂ 1.69 0.23 0.15 C₁₆H₂₇NO₄S₂ 1.69 0.25 0.06 C₁₃H₂₂O₄ 1.69 0.31 0.00 C₁₃H₂₂N₂O₁₉ 1.69 1.46 0.15 C₁₀H₁₇N₃O₇S₂ 1.70 0.70 0.30 C₂₀H₃₄N₂S₅ 1.70 0.00 0.10 C₂₇H₄₆N₄O 1.70 0.04 0.15 C₂₀H₃₄N₁₀OS₃ 1.70 0.05 0.50 C₁₀H₁₇NOS₇ 1.70 0.10 0.10 C₂₃H₃₉N₅O₄S₂ 1.70 0.17 0.22 C₂₀H₃₄N₂O₇S 1.70 0.35 0.10 C₂₈H₄₈S₂ 1.71 0.00 0.00 C₃₅H₆₀N₄ 1.71 0.00 0.11 C₅₆H₉₆N₈ 1.71 0.00 0.14 C₂₈H₄₈N₄O 1.71 0.04 0.14 C₂₈H₄₈N₆OS₅ 1.71 0.04 0.21 C₂₁H₃₆OS₂ 1.71 0.05 0.00 C₂₁H₃₆O₃S₃ 1.71 0.14 0.00 C₂₁H₃₆N₂O₄S 1.71 0.19 0.10 C₁₄H₂₄O₃S₂ 1.71 0.21 0.00 C₁₄H₂₄N₂O₁₈ 1.71 1.29 0.14 C₁₈H₃₁N₉S₃ 1.72 0.00 0.50 C₁₈H₃₁N₃₀S₂ 1.72 0.06 0.17 C₁₈H₃₁N₃O₂S₂ 1.72 0.11 0.17 C₁₈H₃₁N₃O₅S₂ 1.72 0.28 0.17 C₂₂H₃₈N₂S₇ 1.73 0.00 0.09 C₁₅H₂₆N₈S₆ 1.73 0.00 0.53 C₃₇H₆₄OS₄ 1.73 0.03 0.00 C₁₅H₂₆O₃S₂ 1.73 0.20 0.00 C₁₅H₂₆N₂O₃S₂ 1.73 0.20 0.13 C₁₅H₂₆O₄ 1.73 0.27 0.00 C₂₆H₄₅N₅O₁₀S 1.73 0.38 0.19 C₂₂H₃₈O₁₁S 1.73 0.50 0.00 C₂₃H₄₀N₁₀S 1.74 0.00 0.43 C₃₁H₅₄OS₇ 1.74 0.03 0.00 C₃₈H₆₆OS₄ 1.74 0.03 0.00 C₃₁H₅₄N₄O 1.74 0.03 0.13 C₁₉H₃₃N₃OS₂ 1.74 0.05 0.16 C₃₁H₅₄N₄O₂ 1.74 0.06 0.13 C₂₇H₄₇N₅O₂S₄ 1.74 0.07 0.19 C₁₉H₃₃N₃O₂S₂ 1.74 0.11 0.16 C₃₁H₅₄N₂O₄S₂ 1.74 0.13 0.06 C₁₉H₃₃N₅O₄ 1.74 0.21 0.26 C₂₃H₄₀O₇S₂ 1.74 0.30 0.00 C₂₇H₄₇N₅O₁₀S 1.74 0.37 0.19 C₃₂H₅₆N₄ 1.75 0.00 0.13 C₁₆H₂₈N₄S₂ 1.75 0.00 0.25 C₃₂H₅₆N₁₀S₃ 1.75 0.00 0.31 C₁₆H₂₈N₆ 1.75 0.00 0.38 C₂₄H₄₂OS₄ 1.75 0.04 0.00 C₂₀H₃₅N₃OS₄ 1.75 0.05 0.15 C₂₀H₃₅N₃OS₂ 1.75 0.05 0.15 C₂₀H₃₅N₉OS₃ 1.75 0.05 0.45 C₃₆H₆₃NO₂S₄ 1.75 0.06 0.03 C₃₂H₅₆N₄O₂ 1.75 0.06 0.13 C₂₈H₄₉N₅O₂S₄ 1.75 0.07 0.18 C₂₀H₃₅N₅O₂S₂ 1.75 0.10 0.25 C₁₆H₂₈N₂O₂S₂ 1.75 0.13 0.13 C₁₆H₂₈N₂O₃S₂ 1.75 0.19 0.13 C₂₀H₃₅N₅O₄S₃ 1.75 0.20 0.25 C₂₄H₄₂O₅S₃ 1.75 0.21 0.00 C₁₂H₂₁N₃O₃S 1.75 0.25 0.25 C₁₆H₂₈O₅ 1.75 0.31 0.00 C₁₆H₂₈N₄O₈ 1.75 0.50 0.25 C₈H₁₄N₂O₉S₇ 1.75 1.13 0.25 C₁₇H₃₀S₂ 1.76 0.00 0.00 C₃₄H₆₀N₄ 1.76 0.00 0.12 C₁₇H₃₀N₆OS₃ 1.76 0.06 0.35 C₂₁H₃₇NO₂S₃ 1.76 0.10 0.05 C₁₇H₃₀N₄O₂S₂ 1.76 0.12 0.24 C₃₇H₆₅NO₅S₂ 1.76 0.14 0.03 C₁₇H₃₀N₄O₃S₂ 1.76 0.18 0.24 C₁₇H₃₀O₄ 1.76 0.24 0.00 C₃₃H₅₈O₁₁S 1.76 0.33 0.00 C₃₅H₆₂N₄ 1.77 0.00 0.11 C₃₅H₆₂N₄O₂ 1.77 0.06 0.11 C₃₁H₅₅N₅O₃ 1.77 0.10 0.16 C₂₂H₃₉N₁₅O₄S 1.77 0.18 0.68 C₁₈H₃₂N₂S₅ 1.78 0.00 0.11 C₃₇H₆₆N₄ 1.78 0.00 0.11 C₂₇H₄₈N₄ 1.78 0.00 0.15 C₁₈H₃₂N₆S₂ 1.78 0.00 0.33 C₂₇H₄₈N₄OS 1.78 0.04 0.15 C₁₈H₃₂N₁₀OS 1.78 0.06 0.56 C₉H₁₆N₆OS₄ 1.78 0.11 0.67 C₁₈H₃₂N₂O₂S₂ 1.78 0.11 0.11 C₃₇H₆₆O₅S₂ 1.78 0.14 0.00 C₉H₁₆O₂S₇ 1.78 0.22 0.00 C₃₄H₆₁NS₆ 1.79 0.00 0.03 C₂₉H₅₂N₄ 1.79 0.00 0.14 C₂₈H₅₀N₆S₄ 1.79 0.00 0.21 C₂₄H₄₃N₅S₅ 1.79 0.00 0.21 C₂₉H₅₂N₄OS 1.79 0.03 0.14 C₁₉H₃₄N₄OS₂ 1.79 0.05 0.21 C₂₄H₄₃NO₃S₄ 1.79 0.13 0.04 C₂₄H₄₃N₁₁O₅S₃ 1.79 0.21 0.46 C₁₄H₂₅N₉O₄S 1.79 0.29 0.64 C₂₀H₃₆N₂S₄ 1.80 0.00 0.10 C₃₀H₅₄N₄ 1.80 0.00 0.13 C₂₀H₃₆N₁₀OS₃ 1.80 0.05 0.50 C₂₀H₃₆N₁₀O₂S₄ 1.80 0.10 0.50 C₂₀H₃₆N₂O₃S₂ 1.80 0.15 0.10 C₃₀H₅₄N₂O₅S₅ 1.80 0.17 0.07 C₂₀H₃₆N₄O₄S₂ 1.80 0.20 0.20 C₁₀H₁₈O₅ 1.80 0.50 0.00 C₁₆H₂₉N₃S₂ 1.81 0.00 0.19 C₃₁H₅₆N₄OS 1.81 0.03 0.13 C₂₆H₄₇N₅OS₅ 1.81 0.04 0.19 C₂₁H₃₈OS₂ 1.81 0.05 0.00 C₁₆H₂₉NO₂S₂ 1.81 0.13 0.06 C₃₁H₅₆N₁₀O₆S 1.81 0.19 0.32 C₃₁H₅₆N₂O₉S₃ 1.81 0.29 0.06 C₃₄H₆₂N₄S 1.82 0.00 0.12 C₁₁H₂₀N₂S₃ 1.82 0.00 0.18 C₁₇H₃₁N₃S₂ 1.82 0.00 0.18 C₃₃H₆₀N₄O 1.82 0.03 0.12 C₁₇H₃₁N₃OS₂ 1.82 0.06 0.18 C₂₂H₄₀O₂S₄ 1.82 0.09 0.00 C₁₇H₃₁N₃O₅S₂ 1.82 0.29 0.18 C₁₁H₂₀O₅ 1.82 0.45 0.00 C₂₈H₅₁N₅O₁₄ 1.82 0.50 0.18 C₁₂H₂₂N₈O₈ 1.83 0.67 0.67 C₂₃H₄₂N₄S₄ 1.83 0.00 0.17 C₁₂H₂₂N₂S₃ 1.83 0.00 0.17 C₂₄H₄₄N₄S₅ 1.83 0.00 0.17 C₂₄H₄₄N₆S₅ 1.83 0.00 0.25 C₁₈H₃₃N₅OS₂ 1.83 0.06 0.28 C₁₈H₃₃N₃O₂S₂ 1.83 0.11 0.17 C₁₂H₂₂N₂O₂S₂ 1.83 0.17 0.17 C₁₂H₂₂N₂O₃S₅ 1.83 0.25 0.17 C₂₄H₄₄N₂O₇S₅ 1.83 0.29 0.08 C₂₄H₄₄O₁₂S 1.83 0.50 0.00 C₆H₁₁NO₃S₅ 1.83 0.50 0.17 C₁₂H₂₂N₂O₆ 1.83 0.50 0.17 C₁₂H₂₂N₂O₁₈ 1.83 1.50 0.17 C₃₇H₆₈N₈OS₆ 1.84 0.03 0.22 C₁₉H₃₅N₃OS₂ 1.84 0.05 0.16 C₂₅H₄₆N₂O₃S₅ 1.84 0.12 0.08 C₃₂H₅₉NO₄S₅ 1.84 0.13 0.03 C₁₉H₃₅N₅O₆S 1.84 0.32 0.26 C₁₃H₂₄O₉S₂ 1.85 0.69 0.00 C₂₀H₃₇N₅O₁₇ 1.85 0.85 0.25 C₃₃H₆₁NS₅ 1.85 0.00 0.03 C₂₀H₃₇N₃OS₂ 1.85 0.05 0.15 C₁₃H₂₄OS₂ 1.85 0.08 0.00 C₂₆H₄₈N₁₄O₂S 1.85 0.08 0.54 C₂₀H₃₇N₅O₂S₃ 1.85 0.10 0.25 C₂₇H₅₀O₃S₅ 1.85 0.11 0.00 C₂₀H₃₇N₃O₃S₂ 1.85 0.15 0.15 C₂₀H₃₇N₃O₉ 1.85 0.45 0.15 C₂₉H₅₄N₁₀S 1.86 0.00 0.34 C₂₈H₅₂N₄O₄S₄ 1.86 0.14 0.14 C₁₄H₂₆N₄O₇ 1.86 0.50 0.29 C₂₃H₄₃N₁₅S₃ 1.87 0.00 0.65 C₁₅H₂₈N₄S₂ 1.87 0.00 0.27 C₁₅H₂₈N₆S₃ 1.87 0.00 0.40 C₃₀H₅₆N₁₀OS₃ 1.87 0.03 0.33 C₁₅H₂₈O₄ 1.87 0.27 0.00 C₁₇H₃₂N₂S₅ 1.88 0.00 0.12 C₃₂H₆₀N₄S 1.88 0.00 0.13 C₃₄H₆₄N₄OS 1.88 0.03 0.12 C₁₆H₃₀N₄OS₂ 1.88 0.06 0.25 C₁₇H₃₂N₄O₂S₂ 1.88 0.12 0.24 C₂₄H₄₅NO₃S₃ 1.88 0.13 0.04 C₁₇H₃₂O₄ 1.88 0.24 0.00 C₁₆H₃₀O₄ 1.88 0.25 0.00 C₁₉H₃₆N₄O₁₇ 1.89 0.89 0.21 C₃₅H₆₆N₆S₄ 1.89 0.00 0.17 C₁₈H₃₄N₄OS₃ 1.89 0.06 0.22 C₁₈H₃₄N₂O₂S₂ 1.89 0.11 0.11 C₁₉H₃₆N₄O₃S₂ 1.89 0.16 0.21 C₂₇H₅₁NO₇S₃ 1.89 0.26 0.04 C₂₁H₄₀S₂ 1.90 0.00 0.00 C₃₁H₅₉NS₆ 1.90 0.00 0.03 C₂₁H₄₀OS₂ 1.90 0.05 0.00 C₂₁H₄₀N₁₂O₂S₃ 1.90 0.10 0.57 C₂₁H₄₀N₄O₆S 1.90 0.29 0.19 C₁₀H₁₉N₃O₃ 1.90 0.30 0.30 C₁₀H₁₉N₃O₄S 1.90 0.40 0.30 C₃₂H₆₁N₁₁S₃ 1.91 0.00 0.34 C₃₄H₆₅N₃OS₅ 1.91 0.03 0.09 C₂₃H₄₄O₂S₄ 1.91 0.09 0.00 C₂₃H₄₄N₁₆O₃S 1.91 0.13 0.70 C₂₃H₄₄O₃S₄ 1.91 0.13 0.00 C₂₂H₄₂O₈S₃ 1.91 0.36 0.00 C₁₁H₂₁N₃O₄S 1.91 0.36 0.27 C₂₅H₄₈S₅ 1.92 0.00 0.00 C₁₃H₂₅N₃S₃ 1.92 0.00 0.23 C₁₂H₂₃N₃S₃ 1.92 0.00 0.25 C₂₄H₄₆N₆S₄ 1.92 0.00 0.25 C₂₅H₄₈N₁₀S 1.92 0.00 0.40 C₂₆H₅₀O₂S₄ 1.92 0.08 0.00 C₁₃H₂₅N₇OS 1.92 0.08 0.54 C₂₆H₅₀O₁₁S₃ 1.92 0.42 0.00 C₁₄H₂₇N₅O₃S 1.93 0.21 0.36 C₁₈H₃₅N₃OS₂ 1.94 0.06 0.17 C₃₁H₆₀N₂O₄S₅ 1.94 0.13 0.06 C₃₅H₆₈O₆S 1.94 0.17 0.00 C₃₄H₆₆O₆S 1.94 0.18 0.00 C₃₄H₆₆O₇S 1.94 0.21 0.00 C₁₆H₃₁NO₉S 1.94 0.56 0.06 C₂₁H₄₁NOS₄ 1.95 0.05 0.05 C₂₂H₄₃N₁₅O₂S₄ 1.95 0.09 0.68 C₂₂H₄₃N₅O₆S 1.95 0.27 0.23 C₂₂H₄₃N₁₁O₆ 1.95 0.27 0.50 C₂₁H₄₁N₅O₇S₃ 1.95 0.33 0.24 C₂₆H₅₁N₁₇S₃ 1.96 0.00 0.65 C₂₈H₅₅N₁₁S₂ 1.96 0.00 0.39 C₂₃H₄₅N₇OS₃ 1.96 0.04 0.30 C₂₃H₄₅N₁₅O₂S₄ 1.96 0.09 0.65 C₂₇H₅₃NO₃S₅ 1.96 0.11 0.04 C₂₄H₄₇NO₈S₃ 1.96 0.33 0.04 C₂₄H₄₇N₅O₁₀S₂ 1.96 0.42 0.21 C₂₉H₅₇N₁₁S 1.97 0.00 0.38 C₃₀H₅₉NO₃S₅ 1.97 0.10 0.03 C₂₉H₅₇N₃O₈S₂ 1.97 0.28 0.10 C₁₈H₆N₂S₆ 0.33 0.00 0.11 C₁₅H₅N₃S₇ 0.33 0.00 0.20 C₂₄H₈N₄O₅ 0.33 0.21 0.17 C₁₇H₆N₈OS 0.35 0.06 0.47 C₁₇H₆N₄O₅S 0.35 0.29 0.24 C₂₀H₇N₅O₆ 0.35 0.30 0.25 C₁₉H₇N₅O₃ 0.37 0.16 0.26 C₁₉H₇N₃O₆S₇ 0.37 0.32 0.16 C₂₄H₉N₅O₆ 0.38 0.25 0.21 C₂₁H₈N₄O₇ 0.38 0.33 0.19 C₂₃H₉N₅O₄ 0.39 0.17 0.22 C₁₀H₄O₉S₃ 0.40 0.90 0.00 C₂₅H₁₀N₄O₅ 0.40 0.20 0.16 C₂₀H₈N₄O₅ 0.40 0.25 0.20 C₁₀H₄N₂O₃S₈ 0.40 0.30 0.20 C₁₀H₄N₆O₄S₉ 0.40 0.40 0.60 C₁₀H₄N₂O₁₀S₈ 0.40 1.00 0.20 C₁₇H₇N₃S 0.41 0.00 0.18 C₂₂H₉N₅O₅ 0.41 0.23 0.23 C₂₄H₁₀N₄O₄ 0.42 0.17 0.17 C₂₄H₁₀N₄O₆ 0.42 0.25 0.17 C₁₄H₆N₂O₁₀S₈ 0.43 0.71 0.14 C₂₈H₁₂N₈O₅ 0.43 0.18 0.29 C₁₄H₆O₃ 0.43 0.21 0.00 C₂₃H₁₀N₄O₆ 0.43 0.26 0.17 C₂₁H₉N₅O₆ 0.43 0.29 0.24 C₁₄H₆N₄O₄S 0.43 0.29 0.29 C₁₈H₈N₈S 0.44 0.00 0.44 C₃₁H₁₄N₈O₃ 0.45 0.10 0.26 C₂₂H₁₀N₄O₅ 0.45 0.23 0.18 C₂₀H₉N₅O₅ 0.45 0.25 0.25 C₂₀H₉N₅O₆ 0.45 0.30 0.25 C₂₂H₁₀N₄O₇ 0.45 0.32 0.18 C₃₅H₁₆O₄S 0.46 0.11 0.00 C₂₆H₁₂N₄O₅ 0.46 0.19 0.15 C₁₉H₉N₅O₅ 0.47 0.26 0.26 C₁₇H₈N₄O₅ 0.47 0.29 0.24 C₂₃H₁₁N₅O₄ 0.48 0.17 0.22 C₂₅H₁₂N₄O₅ 0.48 0.20 0.16 C₂₃H₁₁N₅O₅ 0.48 0.22 0.22 C₂₁H₁₀N₄O₅ 0.48 0.24 0.19 C₂₁H₁₀N₄O₆ 0.48 0.29 0.19 C₄H₂N₂S₁₀ 0.50 0.00 0.50 C₁₄H₇N₃O₂S 0.50 0.14 0.21 C₂₈H₁₄N₈O₅ 0.50 0.18 0.29 C₂₄H₁₂N₄O₅ 0.50 0.21 0.17 C₂₂H₁₁N₅O₅ 0.50 0.23 0.23 C₁₈H₉N₅O₅ 0.50 0.28 0.28 C₂₄H₁₂N₄O₇ 0.50 0.29 0.17 C₁₂H₆O₁₂S₅ 0.50 1.00 0.00 C₄H₂N₂O₄S₃ 0.50 1.00 0.50 C₃₉H₂₀N₁₀O 0.51 0.03 0.26 C₂₇H₁₄N₄O₅ 0.52 0.19 0.15 C₂₁H₁₁N₅O₄ 0.52 0.19 0.24 C₂₁H₁₁N₅O₆ 0.52 0.29 0.24 C₁₉H₁₀N₄OS₉ 0.53 0.05 0.21 C₁₇H₉N₉O₂S₂ 0.53 0.12 0.53 C₁₉H₁₀N₄O₄ 0.53 0.21 0.21 C₁₇H₉N₅O₅ 0.53 0.29 0.29 C₂₄H₁₃N₅O₃ 0.54 0.13 0.21 C₄₇H₂₆N₄OS 0.55 0.02 0.09 C₂₀H₁₁N₅O₄ 0.55 0.20 0.25 C₂₂H₁₂N₄O₆ 0.55 0.27 0.18 C₁₁H₆O₁₂S₃ 0.55 1.09 0.00 C₃₉H₂₂N₂S 0.56 0.00 0.05 C₉H₅N₃O 0.56 0.11 0.33 C₂₅H₁₄N₄O₅ 0.56 0.20 0.16 C₂₁H₁₂N₄O₅ 0.57 0.24 0.19 C₂₁H₁₂N₁₀O₅S 0.57 0.24 0.48 C₄₅H₂₆ 0.58 0.00 0.00 C₂₄H₁₄N₄O₄ 0.58 0.17 0.17 C₂₄H₁₄N₄O₅ 0.58 0.21 0.17 C₂₄H₁₄N₄O₆ 0.58 0.25 0.17 C₄₁H₂₄ 0.59 0.00 0.00 C₂₂H₁₃N₅O₂ 0.59 0.09 0.23 C₁₇H₁₀O₃S₂ 0.59 0.18 0.00 C₁₆H₁₆S₂ 1.00 0.00 0.00 C₄₄H₄₄N₂ 1.00 0.00 0.05 C₁₇H₁₇NS₂ 1.00 0.00 0.06 C₁₅H₁₅NS₂ 1.00 0.00 0.07 C₂₆H₂₆N₄S₂ 1.00 0.00 0.15 C₄₁H₄₁N₇S 1.00 0.00 0.17 C₂₄H₂₄N₄S₂ 1.00 0.00 0.17 C₃₃H₃₃N₇S₂ 1.00 0.00 0.21 C₁₆H₁₆N₄S₃ 1.00 0.00 0.25 C₄₀H₄₀N₁₂ 1.00 0.00 0.30 C₂₈H₂₈N₁₆ 1.00 0.00 0.57 C₃₄H₃₄N₆OS 1.00 0.03 0.18 C₄₉H₄₉N₃O₂ 1.00 0.04 0.06 C₂₈H₂₈N₂OS 1.00 0.04 0.07 C₁₉H₁₉NOS₂ 1.00 0.05 0.05 C₃₇H₃₇N₃O₂S 1.00 0.05 0.08 C₁₉H₁₉N₃O 1.00 0.05 0.16 C₁₉H₁₉N₅OS 1.00 0.05 0.26 C₁₆H₁₆OS₂ 1.00 0.06 0.00 C₂₉H₂₉NO₂S 1.00 0.07 0.03 C₁₅H₁₅NOS₂ 1.00 0.07 0.07 C₂₀H₂₀O₂S₂ 1.00 0.10 0.00 C₂₁H₂₁NO₂ 1.00 0.10 0.05 C₂₉H₂₉N₁₃O₃ 1.00 0.10 0.45 C₁₉H₁₉NO₂S₂ 1.00 0.11 0.05 C₂₆H₂₆O₃S 1.00 0.12 0.00 C₁₇H₁₇NO₂S₂ 1.00 0.12 0.06 C₃₃H₃₃N₁₃O₄ 1.00 0.12 0.39 C₁₆H₁₆O₂S₂ 1.00 0.13 0.00 C₈H₈N₂OS₆ 1.00 0.13 0.25 C₃₀H₃₀N₈O₅S₂ 1.00 0.17 0.27 C₁₆H₁₆O₃S₂ 1.00 0.19 0.00 C₁₅H₁₅NO₃S₂ 1.00 0.20 0.07 C₂₀H₂₀N₆O₄S₃ 1.00 0.20 0.30 C₂₀H₂₀N₁₀O₄S 1.00 0.20 0.50 C₁₄H₁₄O₃S₂ 1.00 0.21 0.00 C₈H₈O₂ 1.00 0.25 0.00 C₁₃H₁₃N₇O₅S 1.00 0.38 0.54 C₁₀H₁₀O₄ 1.00 0.40 0.00 C₈H₈O₄ 1.00 0.50 0.00 C₉H₉N₃O₅ 1.00 0.56 0.33 C₃₀H₃₁N₁₃ 1.03 0.00 0.43 C₃₀H₃₁NOS 1.03 0.03 0.03 C₃₀H₃₁N₃OS 1.03 0.03 0.10 C₂₉H₃₀N₁₂O 1.03 0.03 0.41 C₂₉H₃₀N₁₂O₂ 1.03 0.07 0.41 C₃₀H₃₁N₁₃O₃ 1.03 0.10 0.43 C₂₇H₂₈S₄ 1.04 0.00 0.00 C₂₈H₂₉NS 1.04 0.00 0.04 C₂₈H₂₉N₁₃ 1.04 0.00 0.46 C₂₅H₂₆OS₄ 1.04 0.04 0.00 C₂₈H₂₉NO₂S 1.04 0.07 0.04 C₂₅H₂₆N₄O₄S 1.04 0.16 0.16 C₄₃H₄₅N₇S 1.05 0.00 0.16 C₂₁H₂₂N₈ 1.05 0.00 0.38 C₂₀H₂₁NO₂S₂ 1.05 0.10 0.05 C₃₉H₄₁N₃O₄S 1.05 0.10 0.08 C₂₂H₂₃NO₃S₂ 1.05 0.14 0.05 C₂₁H₂₂N₄O₅ 1.05 0.24 0.19 C₃₁H₃₃NS 1.06 0.00 0.03 C₁₆H₁₇NS₂ 1.06 0.00 0.06 C₁₇H₁₈N₂S₂ 1.06 0.00 0.12 C₃₆H₃₈N₈S 1.06 0.00 0.22 C₁₆H₁₇NOS₂ 1.06 0.06 0.06 C₃₅H₃₇N₃O₂S 1.06 0.06 0.09 C₃₁H₃₃N₅O₃S₄ 1.06 0.10 0.16 C₁₈H₁₉NO₂S₂ 1.06 0.11 0.06 C₁₇H₁₈O₂S₂ 1.06 0.12 0.00 C₁₆H₁₇NO₂S₂ 1.06 0.13 0.06 C₁₇H₁₈O₃S₂ 1.06 0.18 0.00 C₁₇H₁₈N₈O₃ 1.06 0.18 0.47 C₁₆H₁₇NO₃S₂ 1.06 0.19 0.06 C₁₈H₁₉N₇O₄ 1.06 0.22 0.39 C₁₇H₁₈N₆O₄S₃ 1.06 0.24 0.35 C₁₆H₁₇NO₄S₂ 1.06 0.25 0.06 C₃₀H₃₂N₂S 1.07 0.00 0.07 C₂₈H₃₀N₄S 1.07 0.00 0.14 C₂₈H₃₀N₁₂ 1.07 0.00 0.43 C₂₈H₃₀OS₄ 1.07 0.04 0.00 C₁₅H₁₆OS₂ 1.07 0.07 0.00 C₂₉H₃₁NO₂S 1.07 0.07 0.03 C₁₄H₁₅NOS₂ 1.07 0.07 0.07 C₂₈H₃₀N₂O₂S 1.07 0.07 0.07 C₂₇H₂₉NO₃S 1.07 0.11 0.04 C₁₅H₁₆O₂S₂ 1.07 0.13 0.00 C₁₄H₁₅N₇O₅S 1.07 0.36 0.50 C₂₆H₂₈S₄ 1.08 0.00 0.00 C₂₄H₂₆N₁₀O₂S₃ 1.08 0.08 0.42 C₁₃H₁₄N₆OS 1.08 0.08 0.46 C₂₅H₂₇N₁₃O₂ 1.08 0.08 0.52 C₃₇H₄₀N₄O₄ 1.08 0.11 0.11 C₂₄H₂₆O₄S₂ 1.08 0.17 0.00 C₁₂H₁₃N₇O₄S 1.08 0.33 0.58 C₁₃H₁₄N₆O₅S 1.08 0.38 0.46 C₂₂H₂₄N₆S₅ 1.09 0.00 0.27 C₂₃H₂₅N₉ 1.09 0.00 0.39 C₂₂H₂₄O₂S₂ 1.09 0.09 0.00 C₂₃H₂₅N₁₁O₃S 1.09 0.13 0.48 C₃₅H₃₈O₆S₄ 1.09 0.17 0.00 C₂₂H₂₄O₄ 1.09 0.18 0.00 C₂₂H₂₄N₆O₄ 1.09 0.18 0.27 C₄₀H₄₄N₂S₄ 1.10 0.00 0.05 C₂₁H₂₃NS₄ 1.10 0.00 0.05 C₂₉H₃₂N₈S₂ 1.10 0.00 0.28 C₃₁H₃₄N₄OS₂ 1.10 0.03 0.13 C₃₀H₃₃NO₂S 1.10 0.07 0.03 C₃₁H₃₄N₂O₃S 1.10 0.10 0.06 C₂₉H₃₂N₂O₃S 1.10 0.10 0.07 C₂₀H₂₂N₁₀O₃S 1.10 0.15 0.50 C₂₉H₃₂N₈O₆ 1.10 0.21 0.28 C₂₇H₃₀S₄ 1.11 0.00 0.00 C₂₈H₃₁NS 1.11 0.00 0.04 C₁₉H₂₁N₇ 1.11 0.00 0.37 C₁₉H₂₁NOS₂ 1.11 0.05 0.05 C₃₆H₄₀N₄O₂ 1.11 0.06 0.11 C₁₈H₂₀N₈O 1.11 0.06 0.44 C₁₈H₂₀O₂S₁₀ 1.11 0.11 0.00 C₁₉H₂₁NO₂S₂ 1.11 0.11 0.05 C₁₉H₂₁NO₃S₂ 1.11 0.16 0.05 C₁₈H₂₀N₈O₃ 1.11 0.17 0.44 C₉H₁₀N₆O₂S 1.11 0.22 0.67 C₂₇H₃₀O₁₀S 1.11 0.37 0.00 C₂₅H₂₈S₄ 1.12 0.00 0.00 C₃₄H₃₈N₂S 1.12 0.00 0.06 C₃₃H₃₇N₁₃S₂ 1.12 0.00 0.39 C₂₆H₂₉N₁₅ 1.12 0.00 0.58 C₁₇H₁₉NO₂S₂ 1.12 0.12 0.06 C₂₅H₂₈N₁₂O₄ 1.12 0.16 0.48 C₂₅H₂₈N₈O₅ 1.12 0.20 0.32 C₁₅H₁₇NS₂ 1.13 0.00 0.07 C₁₆H₁₈N₂S₂ 1.13 0.00 0.13 C₂₃H₂₆N₄S₂ 1.13 0.00 0.17 C₃₈H₄₃N₇S 1.13 0.00 0.18 C₃₂H₃₆N₈S₂ 1.13 0.00 0.25 C₁₆H₁₈N₄S₃ 1.13 0.00 0.25 C₃₀H₃₄N₈S₂ 1.13 0.00 0.27 C₂₃H₂₆N₆OS₅ 1.13 0.04 0.26 C₃₈H₄₃N₃O₃S 1.13 0.08 0.08 C₁₆H₁₈O₂S₂ 1.13 0.13 0.00 C₁₅H₁₇NO₂S₂ 1.13 0.13 0.07 C₂₃H₂₆N₈O₃ 1.13 0.13 0.35 C₁₆H₁₈O₃S₂ 1.13 0.19 0.00 C₁₅H₁₇NO₃S₂ 1.13 0.20 0.07 C₁₅H₁₇N₅O₃S 1.13 0.20 0.33 C₁₆H₁₈O₄S₂ 1.13 0.25 0.00 C₃₀H₃₄O₈ 1.13 0.27 0.00 C₈H₉N₅O₄ 1.13 0.50 0.63 C₂₉H₃₃N₁₃ 1.14 0.00 0.45 C₂₉H₃₃N₅OS 1.14 0.03 0.17 C₃₆H₄₁N₇O₂ 1.14 0.06 0.19 C₂₁H₂₄O₂S₂ 1.14 0.10 0.00 C₂₉H₃₃NO₃S 1.14 0.10 0.03 C₂₁H₂₄N₆O₂S₃ 1.14 0.10 0.29 C₂₁H₂₄N₈O₂ 1.14 0.10 0.38 C₁₄H₁₆O₂S₂ 1.14 0.14 0.00 C₁₄H₁₆O₃S₂ 1.14 0.21 0.00 C₂₉H₃₃N₃O₆ 1.14 0.21 0.10 C₁₄H₁₆N₆O₄ 1.14 0.29 0.43 C₁₄H₁₆N₂O₇ 1.14 0.50 0.14 C₂₆H₃₀N₁₈S 1.15 0.00 0.69 C₂₆H₃₀S₄ 1.15 0.00 0.00 C₂₀H₂₃NS₂ 1.15 0.00 0.05 C₃₉H₄₅N₇S 1.15 0.00 0.18 C₂₇H₃₁N₁₃ 1.15 0.00 0.48 C₂₇H₃₁N₁₃O 1.15 0.04 0.48 C₂₇H₃₁N₁₃O₂ 1.15 0.07 0.48 C₁₃H₁₅N₅O 1.15 0.08 0.38 C₂₀H₂₃NO₂S₂ 1.15 0.10 0.05 C₁₃H₁₅NO₂S₂ 1.15 0.15 0.08 C₁₉H₂₂N₆O₁₆ 1.16 0.84 0.32 C₁₉H₂₂N₆S₃ 1.16 0.00 0.32 C₃₂H₃₇N₃O₂S 1.16 0.06 0.09 C₂₅H₂₉N₇O₂S₂ 1.16 0.08 0.28 C₃₂H₃₇N₃O₃S₂ 1.16 0.09 0.09 C₁₉H₂₂N₆O₂ 1.16 0.11 0.32 C₁₉H₂₂N₆O₂S₃ 1.16 0.11 0.32 C₁₉H₂₂N₁₀O₂S 1.16 0.11 0.53 C₄₁H₄₈N₄S₃ 1.17 0.00 0.10 C₂₃H₂₇N₃OS₂ 1.17 0.04 0.13 C₃₅H₄₁N₃O₃S 1.17 0.09 0.09 C₂₃H₂₇N₇O₂ 1.17 0.09 0.30 C₁₈H₂₁NO₂S₂ 1.17 0.11 0.06 C₁₂H₁₄O₂S₃ 1.17 0.17 0.00 C₃₆H₄₂O₆S 1.17 0.17 0.00 C₁₈H₂₁N₇O₃ 1.17 0.17 0.39 C₁₈H₂₁NO₄S₂ 1.17 0.22 0.06 C₁₂H₁₄O₃S₃ 1.17 0.25 0.00 C₁₈H₂₁N₃O₆ 1.17 0.33 0.17 C₂₂H₂₆N₂OS₂ 1.18 0.05 0.09 C₁₇H₂₀OS₂ 1.18 0.06 0.00 C₁₇H₂₀O₂S₂ 1.18 0.12 0.00 C₁₇H₂₀N₈O₂ 1.18 0.12 0.47 C₂₂H₂₆N₈O₃ 1.18 0.14 0.36 C₂₂H₂₆N₈O₄ 1.18 0.18 0.36 C₂₈H₃₃N₃O₆ 1.18 0.21 0.11 C₁₇H₂₀N₆O₄ 1.18 0.24 0.35 C₂₂H₂₆N₈O₉S₃ 1.18 0.41 0.36 C₂₇H₃₂N₈S₂ 1.19 0.00 0.30 C₂₆H₃₁N₁₁ 1.19 0.00 0.42 C₃₂H₃₈N₂OS 1.19 0.03 0.06 C₂₁H₂₅NOS₂ 1.19 0.05 0.05 C₁₆H₁₉NOS₂ 1.19 0.06 0.06 C₂₆H₃₁N₁₃O₂ 1.19 0.08 0.50 C₃₁H₃₇NO₃S 1.19 0.10 0.03 C₁₆H₁₉NO₂S₂ 1.19 0.13 0.06 C₃₂H₃₈N₂O₄S 1.19 0.13 0.06 C₁₆H₁₉NO₃S₂ 1.19 0.19 0.06 C₂₁H₂₅N₇O₄ 1.19 0.19 0.33 C₂₇H₃₂N₈O₆ 1.19 0.22 0.30 C₁₆H₁₉N₇O₅ 1.19 0.31 0.44 C₁₅H₁₈O₉S₂ 1.20 0.60 0.00 C₁₅H₁₈S₂ 1.20 0.00 0.00 C₂₅H₃₀S₄ 1.20 0.00 0.00 C₂₀H₂₄OS₂ 1.20 0.05 0.00 C₁₅H₁₈OS₂ 1.20 0.07 0.00 C₃₀H₃₆O₂S₂ 1.20 0.07 0.00 C₁₀H₁₂OS₃ 1.20 0.10 0.00 C₃₀H₃₆N₂O₃S 1.20 0.10 0.07 C₁₅H₁₈O₂S₂ 1.20 0.13 0.00 C₂₀H₂₄N₁₀O₃S 1.20 0.15 0.50 C₁₅H₁₈O₃S₂ 1.20 0.20 0.00 C₂₀H₂₄N₄O₄ 1.20 0.20 0.20 C₃₀H₃₆O₈ 1.20 0.27 0.00 C₂₈H₃₄N₁₄ 1.21 0.00 0.50 C₃₄H₄₁N₃OS 1.21 0.03 0.09 C₁₄H₁₇NOS₂ 1.21 0.07 0.07 C₁₄H₁₇N₇OS 1.21 0.07 0.50 C₂₄H₂₉N₇O₂S 1.21 0.08 0.29 C₂₄H₂₉N₉O₂ 1.21 0.08 0.38 C₁₉H₂₃N₁₃O₂S 1.21 0.11 0.68 C₁₉H₂₃NO₂S₂ 1.21 0.11 0.05 C₁₉H₂₃N₇O₄ 1.21 0.21 0.37 C₁₈H₂₂N₈O 1.22 0.06 0.44 C₁₈H₂₂O₂S₂ 1.22 0.11 0.00 C₂₃H₂₈N₆O₇S₃ 1.22 0.30 0.26 C₃₀H₃₇NOS 1.23 0.03 0.03 C₃₁H₃₈N₂OS 1.23 0.03 0.06 C₃₀H₃₇N₃OS 1.23 0.03 0.10 C₂₂H₂₇N₃OS₂ 1.23 0.05 0.14 C₂₂H₂₇N₇O₂ 1.23 0.09 0.32 C₂₆H₃₂N₁₂O₃ 1.23 0.12 0.46 C₃₀H₃₇N₁₃O₄ 1.23 0.13 0.43 C₃₅H₄₃N₃O₇ 1.23 0.20 0.09 C₃₁H₃₈N₄O₇ 1.23 0.23 0.13 C₂₁H₂₆N₈O 1.24 0.05 0.38 C₂₁H₂₆N₈O₃ 1.24 0.14 0.38 C₂₁H₂₆N₈O₅ 1.24 0.24 0.38 C₁₇H₂₁N₇O₅ 1.24 0.29 0.41 C₄₀H₅₀S₃ 1.25 0.00 0.00 C₂₄H₃₀N₆S₅ 1.25 0.00 0.25 C₂₄H₃₀N₆S₂ 1.25 0.00 0.25 C₁₆H₂₀N₄S₃ 1.25 0.00 0.25 C₂₀H₂₅N₇ 1.25 0.00 0.35 C₂₈H₃₅N₁₅S₂ 1.25 0.00 0.54 C₂₈H₃₅N₃OS 1.25 0.04 0.11 C₁₆H₂₀N₂O 1.25 0.06 0.13 C₂₀H₂₅N₇O₂ 1.25 0.10 0.35 C₁₂H₁₅N₃O₂ 1.25 0.17 0.25 C₃₂H₄₀O₆S 1.25 0.19 0.00 C₁₆H₂₀O₃S₂ 1.25 0.19 0.00 C₁₆H₂₀N₈O₃ 1.25 0.19 0.50 C₁₉H₂₄S 1.26 0.00 0.00 C₁₉H₂₄N₂S₅ 1.26 0.00 0.11 C₂₃H₂₉N₇S 1.26 0.00 0.30 C₃₄H₄₃N₃OS 1.26 0.03 0.09 C₃₁H₃₉N₃OS 1.26 0.03 0.10 C₁₉H₂₄N₂OS₅ 1.26 0.05 0.11 C₁₉H₂₄N₆OS₃ 1.26 0.05 0.32 C₁₉H₂₄N₈O 1.26 0.05 0.42 C₁₉H₂₄N₆O₂S₃ 1.26 0.11 0.32 C₁₉H₂₄O₄S₂ 1.26 0.21 0.00 C₁₉H₂₄N₈O₄ 1.26 0.21 0.42 C₄₁H₅₂S₄ 1.27 0.00 0.00 C₃₇H₄₇N₃S₃ 1.27 0.00 0.08 C₃₀H₃₈N₂OS 1.27 0.03 0.07 C₃₀H₃₈N₁₄O 1.27 0.03 0.47 C₁₅H₁₉NO₃S₂ 1.27 0.20 0.07 C₂₆H₃₃NO₆S 1.27 0.23 0.04 C₂₆H₃₃NO₈ 1.27 0.31 0.04 C₃₉H₅₀O₄S 1.28 0.10 0.00 C₂₅H₃₂N₈O₄ 1.28 0.16 0.32 C₁₈H₂₃NO₃S₂ 1.28 0.17 0.06 C₃₉H₅₀N₄O₇ 1.28 0.18 0.10 C₁₈H₂₃NO₄S₂ 1.28 0.22 0.06 C₁₇H₂₂N₂S₂ 1.29 0.00 0.12 C₁₇H₂₂N₄S₅ 1.29 0.00 0.24 C₂₈H₃₆N₁₄ 1.29 0.00 0.50 C₃₅H₄₅N₉OS 1.29 0.03 0.26 C₂₁H₂₇N₃OS₂ 1.29 0.05 0.14 C₁₇H₂₂N₈O 1.29 0.06 0.47 C₂₁H₂₇N₉O₂ 1.29 0.10 0.43 C₁₇H₂₂N₂O₂S₅ 1.29 0.12 0.12 C₁₇H₂₂N₂O₂S₂ 1.29 0.12 0.12 C₂₄H₃₁N₉O₄ 1.29 0.17 0.38 C₁₇H₂₂O₃S₂ 1.29 0.18 0.00 C₃₄H₄₄N₄O₆ 1.29 0.18 0.12 C₃₄H₄₄N₂O₇ 1.29 0.21 0.06 C₁₄H₁₈N₄O₃ 1.29 0.21 0.29 C₁₇H₂₂O₄ 1.29 0.24 0.00 C₂₁H₂₇NO₆S 1.29 0.29 0.05 C₂₃H₃₀N₈S₂ 1.30 0.00 0.35 C₂₃H₃₀N₆OS₅ 1.30 0.04 0.26 C₂₀H₂₆N₄OS₂ 1.30 0.05 0.20 C₂₀H₂₆O₂S₂ 1.30 0.10 0.00 C₂₀H₂₆N₈O₂ 1.30 0.10 0.40 C₄₃H₅₆O₅S 1.30 0.12 0.00 C₂₃H₃₀N₈O₃ 1.30 0.13 0.35 C₂₀H₂₆N₈O₄ 1.30 0.20 0.40 C₂₃H₃₀O₈S 1.30 0.35 0.00 C₂₆H₃₄N₁₄S₂ 1.31 0.00 0.54 C₁₆H₂₁N₇O₂S 1.31 0.13 0.44 C₃₅H₄₆N₄O₆ 1.31 0.17 0.11 C₁₆H₂₁NO₃S₂ 1.31 0.19 0.06 C₃₂H₄₂O₈S₂ 1.31 0.25 0.00 C₃₅H₄₆N₄O₁₁ 1.31 0.31 0.11 C₃₄H₄₅N₃S 1.32 0.00 0.09 C₃₈H₅₀N₄S₃ 1.32 0.00 0.11 C₃₄H₄₅N₃OS 1.32 0.03 0.09 C₂₂H₂₉N₉O₂ 1.32 0.09 0.41 C₁₉H₂₅NO₃S₂ 1.32 0.16 0.05 C₃₇H₄₉NO₇S₂ 1.32 0.19 0.03 C₁₅H₂₀S₂ 1.33 0.00 0.00 C₁₈H₂₄N₆S₃ 1.33 0.00 0.33 C₃₀H₄₀N₁₀S₂ 1.33 0.00 0.33 C₂₁H₂₈N₁₀S₃ 1.33 0.00 0.48 C₃₃H₄₄N₈OS₂ 1.33 0.03 0.24 C₃₉H₅₂N₄O₂S₂ 1.33 0.05 0.10 C₁₈H₂₄OS₂ 1.33 0.06 0.00 C₁₈H₂₄N₂OS₅ 1.33 0.06 0.11 C₁₅H₂₀OS₂ 1.33 0.07 0.00 C₁₅H₂₀N₂OS₂ 1.33 0.07 0.13 C₁₅H₂₀N₆OS 1.33 0.07 0.40 C₂₁H₂₈N₈O₂ 1.33 0.10 0.38 C₁₈H₂₄O₂S₂ 1.33 0.11 0.00 C₁₈H₂₄N₈O₂ 1.33 0.11 0.44 C₁₅H₂₀O₂S₂ 1.33 0.13 0.00 C₂₄H₃₂N₈O₃ 1.33 0.13 0.33 C₁₈H₂₄O₃S₂ 1.33 0.17 0.00 C₁₈H₂₄N₂O₃S₂ 1.33 0.17 0.11 C₁₅H₂₀O₃S₂ 1.33 0.20 0.00 C₂₄H₃₂O₅ 1.33 0.21 0.00 C₂₁H₂₈N₈O₅ 1.33 0.24 0.38 C₉H₁₂N₂O₃ 1.33 0.33 0.22 C₆H₈N₂O₇S₁₀ 1.33 1.17 0.33 C₂₉H₃₉N₁₃ 1.34 0.00 0.45 C₃₈H₅₁N₃O₃S₂ 1.34 0.08 0.08 C₃₂H₄₃N₇O₆ 1.34 0.19 0.22 C₂₀H₂₇N₁₃ 1.35 0.00 0.65 C₂₀H₂₇N₉O₂ 1.35 0.10 0.45 C₁₇H₂₃NO₃S₂ 1.35 0.18 0.06 C₁₇H₂₃N₇O₃ 1.35 0.18 0.41 C₁₁H₁₅NO₈S₈ 1.36 0.73 0.09 C₂₂H₃₀N₆S₅ 1.36 0.00 0.27 C₂₈H₃₈N₁₆S₃ 1.36 0.00 0.57 C₂₅H₃₄OS₄ 1.36 0.04 0.00 C₂₈H₃₈N₄O 1.36 0.04 0.14 C₂₂H₃₀N₄OS₂ 1.36 0.05 0.18 C₂₂H₃₀N₈O₃ 1.36 0.14 0.36 C₂₂H₃₀O₇ 1.36 0.32 0.00 C₂₂H₃₀N₄O₉ 1.36 0.41 0.18 C₁₁H₁₅NO₅ 1.36 0.45 0.09 C₁₉H₂₆N₂S₅ 1.37 0.00 0.11 C₁₉H₂₆OS₂ 1.37 0.05 0.00 C₁₉H₂₆N₆OS₃ 1.37 0.05 0.32 C₁₉H₂₆O₂S₂ 1.37 0.11 0.00 C₁₉H₂₆N₆O₂S₃ 1.37 0.11 0.32 C₁₉H₂₆O₃S₂ 1.37 0.16 0.00 C₁₉H₂₆N₆O₄ 1.37 0.21 0.32 C₁₉H₂₆N₈O₄ 1.37 0.21 0.42 C₃₅H₄₈N₄O₉ 1.37 0.26 0.11 C₁₆H₂₂N₂S₅ 1.38 0.00 0.13 C₂₉H₄₀N₄S₂ 1.38 0.00 0.14 C₂₉H₄₀N₄O₂ 1.38 0.07 0.14 C₂₄H₃₃N₉O₂ 1.38 0.08 0.38 C₂₁H₂₉N₉O₂ 1.38 0.10 0.43 C₁₆H₂₂O₂S₂ 1.38 0.13 0.00 C₁₆H₂₂N₂O₂S₂ 1.38 0.13 0.13 C₃₂H₄₄N₄O₄S 1.38 0.13 0.13 C₂₁H₂₉N₉O₃ 1.38 0.14 0.43 C₃₄H₄₇N₅O₆S 1.38 0.18 0.15 C₁₆H₂₂O₃S₂ 1.38 0.19 0.00 C₁₆H₂₂N₂O₃S₅ 1.38 0.19 0.13 C₁₆H₂₂N₂O₄S₅ 1.38 0.25 0.13 C₈H₁₁NO₈S₅ 1.38 1.00 0.13 C₂₃H₃₂N₈S₂ 1.39 0.00 0.35 C₃₃H₄₆N₂O₂S₃ 1.39 0.06 0.06 C₂₃H₃₂N₈O₂S₃ 1.39 0.09 0.35 C₂₈H₃₉NO₄ 1.39 0.14 0.04 C₁₈H₂₅N₇O₄ 1.39 0.22 0.39 C₂₃H₃₂N₈O₆ 1.39 0.26 0.35 C₁₀H₁₄O₆ 1.40 0.60 0.00 C₁₅H₂₁NS₂ 1.40 0.00 0.07 C₂₀H₂₈N₂OS₂ 1.40 0.05 0.10 C₂₀H₂₈N₆OS₃ 1.40 0.05 0.30 C₂₀H₂₈N₂O₂S₂ 1.40 0.10 0.10 C₂₀H₂₈N₆O₂S₃ 1.40 0.10 0.30 C₂₀H₂₈O₃S₂ 1.40 0.15 0.00 C₂₀H₂₈N₂O₃S₂ 1.40 0.15 0.10 C₂₀H₂₈N₈O₃ 1.40 0.15 0.40 C₂₀H₂₈N₂O₄S₂ 1.40 0.20 0.10 C₂₀H₂₈N₈O₄ 1.40 0.20 0.40 C₅₃H₇₄N₁₈O₁₂S₅ 1.40 0.23 0.34 C₁₀H₁₄N₆O₅S 1.40 0.50 0.60 C₁₀H₁₄O₅ 1.40 0.50 0.00 C₁₅H₂₁N₃O₁₇ 1.40 1.13 0.20 C₁₀H₁₄O₁₅ 1.40 1.50 0.00 C₃₄H₄₈N₁₀OS₂ 1.41 0.03 0.29 C₂₉H₄₁N₉OS₂ 1.41 0.03 0.31 C₃₂H₄₅N₁₃O 1.41 0.03 0.41 C₁₇H₂₄OS₂ 1.41 0.06 0.00 C₃₄H₄₈N₁₄O₃ 1.41 0.09 0.41 C₁₇H₂₄O₂S₂ 1.41 0.12 0.00 C₁₇H₂₄N₂O₂S₂ 1.41 0.12 0.12 C₃₂H₄₅NO₄ 1.41 0.13 0.03 C₂₂H₃₁N₉O₃ 1.41 0.14 0.41 C₂₇H₃₈N₁₀O₆ 1.41 0.22 0.37 C₂₂H₃₁NO₅S 1.41 0.23 0.05 C₁₇H₂₄O₄S₂ 1.41 0.24 0.00 C₃₄H₄₈O₁₂ 1.41 0.35 0.00 C₂₄H₃₄S₄ 1.42 0.00 0.00 C₁₉H₂₇N₇S₃ 1.42 0.00 0.37 C₁₂H₁₇N₃OS₂ 1.42 0.08 0.25 C₁₉H₂₇N₃O₂S₂ 1.42 0.11 0.16 C₁₉H₂₇NO₃S₂ 1.42 0.16 0.05 C₃₁H₄₄N₄O₅S 1.42 0.16 0.13 C₃₆H₅₁NO₆S₂ 1.42 0.17 0.03 C₂₄H₃₄O₉S 1.42 0.38 0.00 C₃₀H₄₃N₁₃ 1.43 0.00 0.43 C₁₄H₂₀OS₂ 1.43 0.07 0.00 C₂₁H₃₀N₈O₂ 1.43 0.10 0.38 C₂₃H₃₃N₉O₃ 1.43 0.13 0.39 C₂₁H₃₀N₁₄O₃S 1.43 0.14 0.67 C₁₄H₂₀O₂S₂ 1.43 0.14 0.00 C₂₁H₃₀N₈O₄ 1.43 0.19 0.38 C₁₄H₂₀O₃S₂ 1.43 0.21 0.00 C₁₆H₂₃N₃S₂ 1.44 0.00 0.19 C₁₈H₂₆N₆S₃ 1.44 0.00 0.33 C₃₆H₅₂N₂OS₅ 1.44 0.03 0.06 C₂₇H₃₉N₅O 1.44 0.04 0.19 C₁₈H₂₆OS₂ 1.44 0.06 0.00 C₃₆H₅₂N₄O₂ 1.44 0.06 0.11 C₁₈H₂₆N₂OS₂ 1.44 0.06 0.11 C₁₈H₂₆N₆OS₃ 1.44 0.06 0.33 C₁₈H₂₆O₂S₂ 1.44 0.11 0.00 C₁₈H₂₆N₂O₂S₂ 1.44 0.11 0.11 C₁₈H₂₆N₆O₂S₃ 1.44 0.11 0.33 C₃₉H₅₆O₅S 1.44 0.13 0.00 C₁₆H₂₃NO₂S₂ 1.44 0.13 0.06 C₁₈H₂₆O₃S₂ 1.44 0.17 0.00 C₁₆H₂₃N₃O₃S₄ 1.44 0.19 0.19 C₃₆H₅₂O₁₁ 1.44 0.31 0.00 C₃₃H₄₈S₃ 1.45 0.00 0.00 C₂₉H₄₂N₄ 1.45 0.00 0.14 C₂₂H₃₂N₆S₅ 1.45 0.00 0.27 C₂₂H₃₂N₈S₃ 1.45 0.00 0.36 C₂₀H₂₉N₃OS₂ 1.45 0.05 0.15 C₂₂H₃₂N₆OS₅ 1.45 0.05 0.27 C₃₃H₄₈N₄O₂ 1.45 0.06 0.12 C₁₁H₁₆N₆OS₄ 1.45 0.09 0.55 C₂₉H₄₂N₄O₃ 1.45 0.10 0.14 C₂₀H₂₉N₃O₂S₂ 1.45 0.10 0.15 C₃₈H₅₅NO₇ 1.45 0.18 0.03 C₂₀H₂₉N₇O₄ 1.45 0.20 0.35 C₂₀H₂₉NO₆S 1.45 0.30 0.05 C₂₂H₃₂O₉ 1.45 0.41 0.00 C₁₁H₁₆O₁₄ 1.45 1.27 0.00 C₂₆H₃₈N₈S₂ 1.46 0.00 0.31 C₂₆H₃₈N₈OS₂ 1.46 0.04 0.31 C₂₄H₃₅N₇O₂S₂ 1.46 0.08 0.29 C₂₆H₃₈N₈O₂S₂ 1.46 0.08 0.31 C₂₄H₃₅N₉O₂ 1.46 0.08 0.38 C₂₄H₃₅N₃O₈ 1.46 0.33 0.13 C₁₉H₂₈N₂S₅ 1.47 0.00 0.11 C₃₀H₄₄N₄ 1.47 0.00 0.13 C₃₀H₄₄OS₃ 1.47 0.03 0.00 C₁₉H₂₈OS₂ 1.47 0.05 0.00 C₁₉H₂₈N₂OS₂ 1.47 0.05 0.11 C₁₅H₂₂N₁₀OS 1.47 0.07 0.67 C₁₅H₂₂OS₂ 1.47 0.07 0.00 C₃₀H₄₄N₁₄O₂ 1.47 0.07 0.47 C₁₇H₂₅NO₂S₂ 1.47 0.12 0.06 C₁₅H₂₂O₂S₂ 1.47 0.13 0.00 C₃₂H₄₇NO₄ 1.47 0.13 0.03 C₁₅H₂₂N₂O₂S₅ 1.47 0.13 0.13 C₁₉H₂₈O₃S₂ 1.47 0.16 0.00 C₃₈H₅₆N₄O₇ 1.47 0.18 0.11 C₁₇H₂₅N₇O₃ 1.47 0.18 0.41 C₁₅H₂₂O₃S₂ 1.47 0.20 0.00 C₁₅H₂₂N₂O₃S₅ 1.47 0.20 0.13 C₁₅H₂₂N₄O₃S 1.47 0.20 0.27 C₃₁H₄₆N₄ 1.48 0.00 0.13 C₂₉H₄₃N₉S₂ 1.48 0.00 0.31 C₂₃H₃₄N₈O 1.48 0.04 0.35 C₂₅H₃₇N₉OS₃ 1.48 0.04 0.36 C₂₅H₃₇N₉OS₂ 1.48 0.04 0.36 C₃₁H₄₆N₄O₂ 1.48 0.06 0.13 C₂₉H₄₃NO₄S 1.48 0.14 0.03 C₃₁H₄₆O₆ 1.48 0.19 0.00 C₂₇H₄₀O₅S₂ 1.48 0.19 0.00 C₃₇H₅₅NOS₃ 1.49 0.03 0.03 C₄₁H₆₁NO₂ 1.49 0.05 0.02 C₃₉H₅₈O₄S₂ 1.49 0.10 0.00 C₃₅H₅₂O₆S₂ 1.49 0.17 0.00 C₃₅H₅₂N₄O₇ 1.49 0.20 0.11 C₂₀H₃₀S₂ 1.50 0.00 0.00 C₂₄H₃₆N₂S₄ 1.50 0.00 0.08 C₂₈H₄₂N₄S 1.50 0.00 0.14 C₂₈H₄₂N₁₀S₂ 1.50 0.00 0.36 C₁₆H₂₄OS₂ 1.50 0.06 0.00 C₁₈H₂₇N₃OS₂ 1.50 0.06 0.17 C₃₂H₄₈N₆O₂S₂ 1.50 0.06 0.19 C₁₄H₂₁NOS₃ 1.50 0.07 0.07 C₁₄H₂₁N₇OS 1.50 0.07 0.50 C₁₆H₂₄O₂S₂ 1.50 0.13 0.00 C₁₆H₂₄N₂O₂S₅ 1.50 0.13 0.13 C₁₄H₂₁NO₂S₂ 1.50 0.14 0.07 C₃₆H₅₄O₆S₂ 1.50 0.17 0.00 C₁₈H₂₇N₇O₃ 1.50 0.17 0.39 C₁₆H₂₄O₃S₂ 1.50 0.19 0.00 C₁₈H₂₇N₇O₄ 1.50 0.22 0.39 C₂₂H₃₃N₅O₆ 1.50 0.27 0.23 C₂₆H₃₉N₁₁O₈S 1.50 0.31 0.42 C₂₂H₃₃NO₁₂ 1.50 0.55 0.05 C₈H₁₂O₈ 1.50 1.00 0.00 C₄₁H₆₂OS₄ 1.51 0.02 0.00 C₃₇H₅₆O₅S 1.51 0.14 0.00 C₃₇H₅₆O₈S₂ 1.51 0.22 0.00 C₂₁H₃₂S₂ 1.52 0.00 0.00 C₂₃H₃₅N₇S₂ 1.52 0.00 0.30 C₂₃H₃₅N₉S₂ 1.52 0.00 0.39 C₂₉H₄₄N₄OS₂ 1.52 0.03 0.14 C₂₁H₃₂N₂OS₂ 1.52 0.05 0.10 C₃₁H₄₇NO₅S₂ 1.52 0.16 0.03 C₂₇H₄₁N₃O₆S₄ 1.52 0.22 0.11 C₂₃H₃₅N₅O₅S 1.52 0.22 0.22 C₂₁H₃₂O₉S 1.52 0.43 0.00 C₁₇H₂₆N₂S₂ 1.53 0.00 0.12 C₃₈H₅₈O₂S₄ 1.53 0.05 0.00 C₁₉H₂₉N₃OS₂ 1.53 0.05 0.16 C₁₇H₂₆OS₂ 1.53 0.06 0.00 C₃₂H₄₉NO₂S₄ 1.53 0.06 0.03 C₁₇H₂₆O₂S₂ 1.53 0.12 0.00 C₁₇H₂₆N₂O₂S₂ 1.53 0.12 0.12 C₁₇H₂₆O₄ 1.53 0.24 0.00 C₁₇H₂₆O₄S₂ 1.53 0.24 0.00 C₃₄H₅₂O₁₂ 1.53 0.35 0.00 C₃₀H₄₆N₂O₁₄S 1.53 0.47 0.07 C₂₄H₃₇N₇S₂ 1.54 0.00 0.29 C₄₁H₆₃NO₃ 1.54 0.07 0.02 C₁₃H₂₀OS₂ 1.54 0.08 0.00 C₂₆H₄₀N₁₂O₂ 1.54 0.08 0.46 C₃₇H₅₇N₃O₄S₂ 1.54 0.11 0.08 C₁₃H₂₀N₂O₂S₂ 1.54 0.15 0.15 C₃₅H₅₄O₇S₂ 1.54 0.20 0.00 C₁₃H₂₀O₃S₂ 1.54 0.23 0.00 C₁₃H₂₀N₂O₁₉ 1.54 1.46 0.15 C₁₁H₁₇N₇O₇S 1.55 0.64 0.64 C₂₀H₃₁N₇ 1.55 0.00 0.35 C₂₂H₃₄OS₂ 1.55 0.05 0.00 C₂₂H₃₄O₂S₂ 1.55 0.09 0.00 C₂₂H₃₄N₈O₂ 1.55 0.09 0.36 C₂₀H₃₁NO₂S₂ 1.55 0.10 0.05 C₂₀H₃₁N₇O₃ 1.55 0.15 0.35 C₁₈H₂₈N₂S₅ 1.56 0.00 0.11 C₂₇H₄₂N₄S₄ 1.56 0.00 0.15 C₂₅H₃₉N₉S₂ 1.56 0.00 0.36 C₂₅H₃₉N₁₁S₂ 1.56 0.00 0.44 C₂₇H₄₂N₈OS₂ 1.56 0.04 0.30 C₁₈H₂₈OS₂ 1.56 0.06 0.00 C₁₈H₂₈N₄OS₂ 1.56 0.06 0.22 C₁₈H₂₈O₂S₂ 1.56 0.11 0.00 C₃₆H₅₆N₄O₆ 1.56 0.17 0.11 C₂₇H₄₂O₆S 1.56 0.22 0.00 C₁₈H₂₈N₆O₄ 1.56 0.22 0.33 C₂₅H₃₉N₅O₆S₂ 1.56 0.24 0.20 C₁₈H₂₈N₁₂O₇ 1.56 0.39 0.67 C₁₄H₂₂O₉S₂ 1.57 0.64 0.00 C₇H₁₁NO₅ 1.57 0.71 0.14 C₁₄H₂₂O₃S₂ 1.57 0.21 0.00 C₂₈H₄₄N₁₀O₈ 1.57 0.29 0.36 C₂₃H₃₆N₈O₁₀S₂ 1.57 0.43 0.35 C₁₄H₂₂N₂O₁₉ 1.57 1.36 0.14 C₁₉H₃₀N₂S₅ 1.58 0.00 0.11 C₁₉H₃₀OS₂ 1.58 0.05 0.00 C₃₈H₆₀N₄O₃S₂ 1.58 0.08 0.11 C₁₉H₃₀O₂S₂ 1.58 0.11 0.00 C₁₉H₃₀N₆O₂S₃ 1.58 0.11 0.32 C₁₉H₃₀O₃S₂ 1.58 0.16 0.00 C₂₄H₃₈O₅S₂ 1.58 0.21 0.00 C₁₉H₃₀O₈S 1.58 0.42 0.00 C₁₉H₃₀N₁₂O₉S₃ 1.58 0.47 0.63 C₁₂H₁₉N₅O₇ 1.58 0.58 0.42 C₂₉H₄₆N₁₀OS₂ 1.59 0.03 0.34 C₁₇H₂₇N₃OS₂ 1.59 0.06 0.18 C₃₄H₅₄O₆ 1.59 0.18 0.00 C₁₇H₂₇N₅O₄ 1.59 0.24 0.29 C₃₂H₅₁NO₁₀S₂ 1.59 0.31 0.03 C₂₂H₄₄O₁₄S 2.00 0.64 0.00 C₂₁H₄₂O₁₃S 2.00 0.62 0.00 C₁₇H₃₄N₂O₁₄S₂ 2.00 0.82 0.12 C₂₄H₄₈N₁₆S₃ 2.00 0.00 0.67 C₁₆H₃₂N₁₀S₃ 2.00 0.00 0.63 C₂₂H₄₄S₂ 2.00 0.00 0.00 C₂₁H₄₂S₄ 2.00 0.00 0.00 C₂₅H₅₀S₂ 2.00 0.00 0.00 C₉H₁₈S₈ 2.00 0.00 0.00 C₃₄H₆₈N₂S₆ 2.00 0.00 0.06 C₂₅H₅₀N₄S₅ 2.00 0.00 0.16 C₁₇H₃₄N₄S₂ 2.00 0.00 0.24 C₈H₁₆N₂S₃ 2.00 0.00 0.25 C₁₆H₃₂N₄S₂ 2.00 0.00 0.25 C₁₄H₂₈N₆S₃ 2.00 0.00 0.43 C₁₃H₂₆N₆S 2.00 0.00 0.46 C₃₀H₆₀OS₆ 2.00 0.03 0.00 C₂₉H₅₈N₆OS₅ 2.00 0.03 0.21 C₁₉H₃₈N₁₂OS₃ 2.00 0.05 0.63 C₁₉H₃₈OS₂ 2.00 0.05 0.00 C₁₉H₃₈N₆OS₂ 2.00 0.05 0.32 C₁₄H₂₈N₂OS₂ 2.00 0.07 0.14 C₁₅H₃₀N₆OS₃ 2.00 0.07 0.40 C₁₃H₂₆N₆OS 2.00 0.08 0.46 C₂₃H₄₆N₁₆O₂S 2.00 0.09 0.70 C₂₉H₅₈N₂O₃S₅ 2.00 0.10 0.07 C₂₇H₅₄N₈O₃S₃ 2.00 0.11 0.30 C₁₉H₃₈N₆O₂S₄ 2.00 0.11 0.32 C₁₇H₃₄N₁₀O₂S₃ 2.00 0.12 0.59 C₁₄H₂₈O₂S₃ 2.00 0.14 0.00 C₁₃H₂₆N₆O₂S 2.00 0.15 0.46 C₃₂H₆₄O₅S 2.00 0.16 0.00 C₂₆H₅₂N₂O₅S₅ 2.00 0.19 0.08 C₁₆H₃₂N₂O₃S₃ 2.00 0.19 0.13 C₁₄H₂₈O₃ 2.00 0.21 0.00 C₂₆H₅₂N₁₂O₆S 2.00 0.23 0.46 C₂₈H₅₆N₆O₇S₃ 2.00 0.25 0.21 C₁₁H₂₂N₂O₃S₅ 2.00 0.27 0.18 C₂₇H₅₄N₄O₈S 2.00 0.30 0.15 C₂₉H₅₈N₂O₁₀S₃ 2.00 0.34 0.07 C₂₇H₅₄N₂O₁₀S₃ 2.00 0.37 0.07 C₂₅H₅₀O₁₁S₃ 2.00 0.44 0.00 C₂₀H₄₀N₂O₁₀ 2.00 0.50 0.10 C₁₀H₂₀N₂O₅S 2.00 0.50 0.20 C₁₅H₃₀N₂O₈S 2.00 0.53 0.13 C₃₆H₇₂N₁₈O₁₉ 2.00 0.53 0.50 C₁₃H₂₆N₈O₇S 2.00 0.54 0.62 C₆H₁₂O₇ 2.00 1.17 0.00 C₁₃H₂₆N₂O₁₈ 2.00 1.38 0.15 C₃₂H₆₅N₃OS₅ 2.03 0.03 0.09 C₂₃H₄₇N₁₁OS₃ 2.04 0.04 0.48 C₂₆H₅₃NO₂S₂ 2.04 0.08 0.04 C₂₆H₅₃N₅O₂S₄ 2.04 0.08 0.19 C₂₆H₅₃N₅O₂S₂ 2.04 0.08 0.19 C₂₆H₅₃NO₅S₅ 2.04 0.19 0.04 C₂₅H₅₁N₅O₈S 2.04 0.32 0.20 C₂₈H₅₇N₇O₁₁S 2.04 0.39 0.25 C₂₆H₅₃NO₁₁S₃ 2.04 0.42 0.04 C₂₄H₄₉N₅O₁₀S 2.04 0.42 0.21 C₂₃H₄₇N₅O₁₀S 2.04 0.43 0.22 C₁₉H₃₉NO₃S₂ 2.05 0.16 0.05 C₂₁H₄₃N₅O₆S₃ 2.05 0.29 0.24 C₂₁H₄₃N₃O₇S₂ 2.05 0.33 0.14 C₂₀H₄₁N₁₁O₁₁ 2.05 0.55 0.55 C₂₁H₄₃NO₁₂S 2.05 0.57 0.05 C₁₇H₃₅N₁₁O₁₃ 2.06 0.76 0.65 C₃₄H₇₀S₃ 2.06 0.00 0.00 C₃₃H₆₈O₄S 2.06 0.12 0.00 C₁₇H₃₅N₉O₂S₃ 2.06 0.12 0.53 C₁₆H₃₃N₉O₂S₃ 2.06 0.13 0.56 C₃₁H₆₄O₅S 2.06 0.16 0.00 C₃₂H₆₆O₇S₂ 2.06 0.22 0.00 C₁₄H₂₉N₃O₂S₂ 2.07 0.14 0.21 C₂₉H₆₀O₇S₅ 2.07 0.24 0.00 C₂₇H₅₆N₈O₇S₃ 2.07 0.26 0.30 C₂₉H₆₀N₆O₈S 2.07 0.28 0.21 C₁₃H₂₇N₉S 2.08 0.00 0.69 C₁₃H₂₇N₃S₂ 2.08 0.00 0.23 C₂₆H₅₄N₁₀S 2.08 0.00 0.38 C₂₆H₅₄N₂O₄S 2.08 0.15 0.08 C₂₅H₅₂N₂O₉S₃ 2.08 0.36 0.08 C₁₃H₂₇N₅O₅S₂ 2.08 0.38 0.38 C₂₆H₅₄N₂O₁₃S 2.08 0.50 0.08 C₁₁H₂₃NO₉ 2.09 0.82 0.09 C₂₃H₄₈N₂O₇S 2.09 0.30 0.09 C₂₃H₄₈N₂O₈S 2.09 0.35 0.09 C₁₁H₂₃N₃O₄S 2.09 0.36 0.27 C₂₃H₄₈N₄O₁₀ 2.09 0.43 0.17 C₂₀H₄₂N₁₂O₁₅ 2.10 0.75 0.60 C₂₀H₄₂S₃ 2.10 0.00 0.00 C₃₁H₆₅N₁₇O 2.10 0.03 0.55 C₁₀H₂₁N₃O₂S₅ 2.10 0.20 0.30 C₂₀H₄₂N₂O₅S 2.10 0.25 0.10 C₂₀H₄₂N₂O₆S 2.10 0.30 0.10 C₂₀H₄₂N₂O₆S₃ 2.10 0.30 0.10 C₂₁H₄₄O₉S₂ 2.10 0.43 0.00 C₂₈H₅₉NS₇ 2.11 0.00 0.04 C₁₈H₃₈N₁₀OS₄ 2.11 0.06 0.56 C₂₈H₅₉N₃O₆S 2.11 0.21 0.11 C₉H₁₉N₃O₂S₅ 2.11 0.22 0.33 C₁₈H₃₈O₆S₃ 2.11 0.33 0.00 C₁₇H₃₆N₆S₃ 2.12 0.00 0.35 C₂₆H₅₅N₅O₄S₃ 2.12 0.15 0.19 C₂₅H₅₃N₅O₁₀S 2.12 0.40 0.20 C₂₅H₅₃N₃O₁₁S₄ 2.12 0.44 0.12 C₃₃H₇₀N₂O₁₅S₃ 2.12 0.45 0.06 C₂₆H₅₅NO₁₃S₂ 2.12 0.50 0.04 C₁₆H₃₄N₂S₅ 2.13 0.00 0.13 C₃₀H₆₄N₁₀S 2.13 0.00 0.33 C₁₅H₃₂N₆S₃ 2.13 0.00 0.40 C₁₅H₃₂N₆S 2.13 0.00 0.40 C₁₆H₃₄N₄OS 2.13 0.06 0.25 C₂₃H₄₉N₃O₆S 2.13 0.26 0.13 C₂₄H₅₁NO₇S₃ 2.13 0.29 0.04 C₂₄H₅₁NO₁₂S₂ 2.13 0.50 0.04 C₁₆H₃₄N₂O₈S 2.13 0.50 0.13 C₂₉H₆₂N₁₀S 2.14 0.00 0.34 C₂₈H₆₀N₁₀S 2.14 0.00 0.36 C₁₄H₃₀N₆S₃ 2.14 0.00 0.43 C₂₁H₄₅NO₃S₄ 2.14 0.14 0.05 C₂₁H₄₅N₇O₃S₃ 2.14 0.14 0.33 C₂₉H₆₂N₂O₅S₂ 2.14 0.17 0.07 C₂₂H₄₇NO₄S₅ 2.14 0.18 0.05 C₂₉H₆₂N₂O₆S₂ 2.14 0.21 0.07 C₃₅H₇₅N₃O₉ 2.14 0.26 0.09 C₂₀H₄₃N₇O₁₂S₂ 2.15 0.60 0.35 C₂₇H₅₈N₁₀S 2.15 0.00 0.37 C₂₆H₅₆N₁₀S 2.15 0.00 0.38 C₂₇H₅₈N₂O₂S 2.15 0.07 0.07 C₁₃H₂₈N₆OS 2.15 0.08 0.46 C₂₆H₅₆N₂O₃S 2.15 0.12 0.08 C₁₃H₂₈O₂S₃ 2.15 0.15 0.00 C₂₀H₄₃NO₃S₂ 2.15 0.15 0.05 C₁₃H₂₈N₆O₂S 2.15 0.15 0.46 C₂₇H₅₈N₂O₅ 2.15 0.19 0.07 C₂₅H₅₄N₁₀S 2.16 0.00 0.40 C₁₉H₄₁N₉OS₃ 2.16 0.05 0.47 C₁₉H₄₁N₁₁OS₃ 2.16 0.05 0.58 C₂₅H₅₄N₁₆O₂S₂ 2.16 0.08 0.64 C₂₅H₅₄N₂O₂S 2.16 0.08 0.08 C₂₃H₅₀N₆S₄ 2.17 0.00 0.26 C₂₄H₅₂N₂O₂S 2.17 0.08 0.08 C₂₃H₅₀N₂O₂S₄ 2.17 0.09 0.09 C₂₄H₅₂N₂O₃S 2.17 0.13 0.08 C₁₂H₂₆N₈O₂S₆ 2.17 0.17 0.67 C₁₂H₂₆N₆O₂S 2.17 0.17 0.50 C₂₉H₆₃N₅O₇S₂ 2.17 0.24 0.17 C₂₄H₅₂N₂O₆S₃ 2.17 0.25 0.08 C₂₉H₆₃N₃O₈S₂ 2.17 0.28 0.10 C₁₈H₃₉N₅O₅S₂ 2.17 0.28 0.28 C₁₂H₂₆N₂O₁₈ 2.17 1.50 0.17 C₂₂H₄₈N₂O₂₀ 2.18 0.91 0.09 C₂₂H₄₈N₂O₁₂S 2.18 0.55 0.09 C₂₁H₄₆N₂O₁₈ 2.19 0.86 0.10 C₂₁H₄₆N₂O₃S₄ 2.19 0.14 0.10 C₂₁H₄₆N₆O₁₂ 2.19 0.57 0.29 C₁₅H₃₃N₉S₃ 2.20 0.00 0.60 C₁₀H₂₂N₂O₂S₅ 2.20 0.20 0.20 C₂₀H₄₄N₂O₅S 2.20 0.25 0.10 C₂₀H₄₄N₁₀O₇S₃ 2.20 0.35 0.50 C₂₉H₆₄N₁₀S 2.21 0.00 0.34 C₂₃H₅₁N₇O₁₄ 2.22 0.61 0.30 C₂₇H₆₀N₁₀S 2.22 0.00 0.37 C₂₃H₅₁N₃OS₄ 2.22 0.04 0.13 C₂₃H₅₁N₃O₉ 2.22 0.39 0.13 C₂₆H₅₈N₁₀S 2.23 0.00 0.38 C₂₁H₄₇N₇O₁₃S₂ 2.24 0.62 0.33 C₂₅H₅₆N₁₂O₅S 2.24 0.20 0.48 C₂₄H₅₄N₁₆S₃ 2.25 0.00 0.67 C₈H₁₈N₂S₃ 2.25 0.00 0.25 C₈H₁₈N₂OS₃ 2.25 0.13 0.25 C₁₂H₂₇N₃O₂S₅ 2.25 0.17 0.25 C₁₂H₂₇N₇O₄S 2.25 0.33 0.58 C₈H₁₈N₂O₉ 2.25 1.13 0.25

The molecular formulas determined by FTICR-MS can be categorized into compound classes, with some overlap, according to oxygen to carbon (0/C) and hydrogen to carbon (H/C) ratios.³ Compound classification boundaries are displayed in Table 6.

TABLE 6 H/C and O/C Ratio Based Compound Classification Boundaries H/C Compound Type Ratio O/C Ratio Lipid, Protein and Other Aliphatic 1.5-2.2 0-0.67 (LPOA) Lignin 0.7-1.5 0.1-0.67   Condensed Aromatic 0.2-0.7 0-0.67 Carbohydrate 1.5-2.4 0.67-1.2    Unsaturated Hydrocarbon 0.7-1.5 0-0.1 

Table 7 displays the percent of total molecular formulas assigned to each compound classification using H/C and O/C boundaries. The actual number of assigned molecular formulas is presented in parentheses. The compound classification percentages of the semi-humic composition fall between the standard humic extract and blood meal solution for LPOA, lignin, condensed aromatic and carbohydrate compound classes. However, there is a notable increase in the percent unsaturated hydrocarbon for the semi-humic composition as compared to the other samples.

TABLE 7 Compound Classification of Molecular Formulas using H/C and O/C Boundaries Unsatu- Con- rated densed Carbo- Hydro- Uncate- Sample LPOA Lignin Aromatic hydrate carbon gorized Semi-Humic 37.0% 26.5% 9.0% 1.5% 28.5% 2.7% Composition (742) (532) (181) (31) (573) (54) Standard 28.3% 27.4% 19.3%  1.3% 24.8% 2.5% Humic (482) (467) (328) (22) (423) (43) Extract Blood Meal 48.8% 22.0% 2.3% 3.4% 25.4% 3.0% Solution (706) (318)  (34) (49) (368) (44) *Percentages of compound classifications for each sample type do not add up to 100% due to overlap of compound classification boundaries

An alternative compound classification method uses a Modified Aromaticity Index (AI_(mod)) which can be calculated using an established formula based on the elemental components that make up a molecular formula.⁴ Table 8 displays the compound classification boundaries for AI_(mod).

TABLE 8 Modified Aromaticity Index (AI_(mod)) Based Compound Classification Boundaries Compound Type AI_(mod) Non-Aromatic ≦0.5 Aromatic >0.5 & ≦0.67 Condensed Aromatic >0.67

Table 9 displays the percent of total molecular formulas assigned to each compound classification using AI_(mod). The AI_(mod) compound classification percentages for the semi-humic composition fall between the standard humic extract and blood meal solution for non-aromatic and condensed aromatic compound classes. The aromatic compound class, on the other hand, shows a marked increase for the semi-humic composition as compared to the other samples. The difference in percent condensed aromatics calculated with AI_(mod) vs H/C and O/C boundaries could be due to inclusion of some lignin components as condensed aromatics when using AI_(mod).

TABLE 9 Compound Classification of Molecular Formulas using AI_(mod) Non- Condensed Sample Aromatic Aromatic Aromatic Uncategorized Semi-Humic 60.7% 19.3% 19.8% 0.2% Composition (1217) (387) (396) (4) Standard Humic 48.4% 15.3% 36.0% 0.3% Extract  (824) (260) (613) (5) Blood Meal 71.4% 12.5% 15.8% 0.3% Solution (1033) (181) (228) (4)

Tables 10 and 11 display the compound classification percentages of the 1507 unique molecular formulas in the semi-humic composition using both H/C and O/C boundaries as well as AI_(mod). The majority of the unique formulas for the semi-humic composition are classified as either LPOA using H/C and O/C boundaries or non-aromatic when using AI_(mod).

TABLE 10 Compound Classification of the 1507 Unique Molecular Formulas in the Semi-Humic Composition using H/C and O/C Boundaries Unsatu- Con- rated densed Carbo- Hydro- Uncate- Sample LPOA Lignin Aromatic hydrate carbon gorized Semi-Humic 34.2% 24.7% 8.6% 1.0% 28.6% 2.8% Composition (532) (384) (133) (16) (445) (44)

TABLE 11 Compound Classification of the 1507 Unique Molecular Formulas in the Semi-Humic Composition using AI_(mod) Non- Condensed Sample Aromatic Aromatic Aromatic Uncategorized Semi-Humic 61.1% 20.2% 18.7% 0.1% Composition (919) (304) (282) (2)

Van Krevelen diagrams allow for a convenient visual representation of FTICR-MS data. Each point in a Van Krevelen diagram represents a molecular formula with a defined H/C, O/C and/or N/C ratio.⁵ FIGS. 3A and 4A show Van Krevelen Diagrams of the standard humic acid, blood meal solution and semi-humic composition. FIGS. 3B and 4B show Van Krevelen Diagrams of the semi-humic composition alone.

Conclusion

The ultra-high resolution and mass accuracy of FTICR-MS has allowed for the identification of molecular formulas between m/z 120-700 in the semi-humic composition, standard humic acid and blood meal solution. Results show that all three samples are composed of a significant number of unique molecular formulas. The majority of unique formulas in the semi-humic composition are made up of either LPOA or non-aromatic compounds, depending on the compound classification boundaries used. Further, when compared to the other samples the semi-humic composition has more unsaturated hydrocarbon and an increase in aromatic compounds. The increase in unsaturated hydrocarbon could be the result of base catalyzed elimination reactions. The increase in aromatic compounds, on the other hand, could be the result of the breakdown of larger condensed aromatics or lignin.

REFERENCES

-   1. Marshall, Alan G., Christopher L. Hendrickson, and George S.     Jackson. “Fourier transform ion cyclotron resonance mass     spectrometry: a primer.” Mass spectrometry reviews 17.1 (1998):     1-35. -   2. Stubbins, Aron, et al. “Illuminated darkness: Molecular     signatures of Congo River dissolved organic matter and its     photochemical alteration as revealed by ultrahigh precision mass     spectrometry.” Limnology and Oceanography 55.4 (2010): 1467-1477. -   3. Ikeya, Kosuke, et al. “Characterization of the chemical     composition of soil humic acids using Fourier transform ion     cyclotron resonance mass spectrometry.” Geochimica et Cosmochimica     Acta 153 (2015): 169-182. -   4. Blackburn, J. W. T, et al. “Laser desorption/ionization coupled     to FT-ICR mass spectrometry for studies of natural organic matter.”     Analytical Chemistry Published online 23 Mar. 2017 -   5. Kim, Sunghwan, Robert W. Kramer, and Patrick G. Hatcher.     “Graphical method for analysis of ultrahigh-resolution broadband     mass spectra of natural organic matter, the van Krevelen diagram.”     Analytical Chemistry 75.20 (2003): 5336-5344.

Example 3: Mixing a Standard Humic Extract with Blood Meal does not Result in a Flowable Liquid for Use in Agriculture

The semi-humic composition previously described is made up of humic extracts as well blood meal components. In this example a standard humic extract is heated then mixed with blood meal at rates equivalent to the semi-humic composition. This mixture is hereby referred to as Comparison Composition 1.

Methods

Sample Preparation.

A semi-humic composition was prepared as described herein (e.g., FIG. 1B, pH of about 14, mixing at 160° F. for 2 hours). The standard humic extract was prepared by combining 172 g of dry leonardite, 731 g of water and 97 g of 50% (w/w) KOH solution. After mixing for 3 hours, the insoluble residue was removed and the supernatant was isolated resulting in a composition having a pH of about 12. The standard humic extract was heated to 160° F. then mixed with blood meal by stirring with a magnetic stir bar for 1 hour at an equivalent rate to the semi-humic composition, to produce the Comparison Composition 1. Longer mixing times for Comparison Composition 1 were not possible due to phase change, i.e., formation of a gelled material. Table 12 displays the theoretical nitrogen and carbon values of the semi-humic composition and Comparison Composition 1.

TABLE 12 Nitrogen and Carbon Components of the Semi-Humic Composition and Comparison Composition 1 Leonardite- Total Total Derived Sample Nitrogen % Carbon % Total Carbon % Semi-Humic 3 13 2.94 Flowable Composition liquid Comparison  3*  13* 2.94* Gelled solid Composition 1 *Theoretical percentages, although no final liquid composition could be formed.

Results

Soon after adding blood meal to the hot standard humic extract, the Comparison Composition 1 solidified. In contrast, the finished semi-humic composition maintains a viscosity of less than 50 cP for a period of at least 3-6 months.

Conclusion

The Comparison Composition 1 does not result in a flowable liquid product for use in agriculture. The semi-humic composition, on the other hand, remains in a flowable liquid phase for months and is ideally suited for use as an agricultural liquid.

Example 4: Nitrogen Mineralization of the Semi-Humic Composition

Ammonium (NH₄+) and Nitrate (NO₃−) are the primary sources of Nitrogen directly used by most plants. When organic Nitrogen is used as a source of Nitrogen for fertilization, mineralization into ammonium and nitrate forms is required before uptake by most plants. The challenge when using organic Nitrogen as a fertilizer is synchronizing the timing of mineralization with plant demand. Nutrient release curves help determine the correct timing and application rate of organic Nitrogen fertilizers so that Nitrogen is available during the period of plant demand.

Methods

Rosamond Loam soil was collected and prepped by passing material through a 4 mm sieve, mixed thoroughly and stored at 4° C. for no more than two weeks. Next, soil moisture content was determined and moisture content was then adjusted to 55% water filled pore space (WFPS) using a plant mister.^(1,2,3) Glass jars with caps containing 1 mm holes for gas exchange were filled with 125 g of soil. Each jar of soil underwent 7 days of pre-incubation at 25° C. in which caps were removed for 1 hour per day and moisture content was corrected to 55% WFPS every 2 days. Soil treatments included the Semi-Humic Composition, Blood Meal Granules and Soil Alone. For each treatment, soil Nitrogen mineralization was measured at three time points (1, 2, 4 and 8 weeks) with three separate jars at each time point.

Results

Table 13 summarizes the treatments and rates of Nitrogen applied. Throughout the incubation period moisture content was maintained at 55% WFPS.

TABLE 13 Rates and Treatments Field Equivalent Total Treatment Rate Sampling Time Replications Jars Soil Alone — 0, 1, 2, 4 and 8 3 12 weeks Semi-Humic 300 lbs N/ac 1, 2, 4 and 8 weeks 3 9 Composition* Blood Meal 300 lbs N/ac 1, 2, 4 and 8 weeks 3 9 Granules *The material used was Composition 1 (see also Examples 1 and 5)

FIG. 5 summarizes results of soil Nitrogen mineralization over an eight week period. For weeks 2, 4 and 8 ANOVA results between treatments are significant (p<0.05). For week 1, ANOVA results are not significant between the Semi-Humic Composition and Blood Meal Granules treatments.

Conclusion

The Semi-Humic Composition provides more mineralized Nitrogen at two weeks and four weeks compared to Blood Meal Granules at the same rate of Nitrogen. In addition, the standard deviations of measured mineralized soil Nitrogen at each time point from the Semi-Humic Composition are almost an order of magnitude smaller than the Blood Meal Granules treatment. This suggests that the Semi-Humic Composition can provide faster and more consistent mineralized Nitrogen to meet plant demand.

REFERENCES

-   1. Abbasi, M. K., et al. “Impact of the addition of different plant     residues on carbon-nitrogen content and nitrogen     mineralization-immobilization turnover in a soil incubated under     laboratory conditions.” Solid Earth Discussions 6 (2014): 3051-3074. -   2. Honeycutt, C. W., et al. “Protocols for nationally coordinated     laboratory and field research on manure nitrogen mineralization.”     Communications in soil science and plant analysis 36.19-20 (2005):     2807-2822. -   3. Goos, R. J. “A laboratory exercise to demonstrate nitrogen     mineralization and immobilization.” Journal of Natural Resources and     Life Sciences Education 24.1 (1995): 68-70.

Example 5: Effect of the New Substance on Plant Growth

Introduction

The semi-humic composition as prepared in Example 1 (Composition 1) could be a valuable tool for use in organic farming. It is contemplated that forms of Nitrogen in Composition 1 will mineralize more rapidly than other organic Nitrogen sources (animal manure, green manure or compost, blood meal, etc.). Moreover, Composition 1, a liquid suspension, will be easier to apply at lower application rates than many other organic Nitrogen sources. The purpose of this study was to evaluate how plant growth is affected by Composition 1, in comparison to other organic Nitrogen sources.

Materials and Methods

Soil

The soil used was a Rosamond Loam soil collected in Lancaster, Calif. mixed with vermiculite at a 70:30 ratio by weight.

Plants and Transplanting

Commercially available pepper plants were raised from seed and transplanted, one plant per pot, into small pots (length× width× height=4 inches×4 inches×6 inches) on Day 0. Five plants were tested per treatment. Pots were arranged in a randomized complete block design on benches in the greenhouse at the Actagro R&D Facility in Biola, Calif. Temperatures ranged from 68 F to 87 F during the study. Macro and micro nutrients other than nitrogen were applied equally to all pots, to ensure that other nutrients were not limiting.

Nitrogen Sources and Nitrogen Application

Treatments were designed to match nitrogen rate at two levels for each treatment of interest. Liquid treatments were measured and applied by hand to the soil surface using a syringe on Day 0. The second application was made on Day 14. In the case of the dry blood meal treatments the material was spread on the soil surface in a circular pattern about one inch from the base of the pepper plants. The treatment list is shown in Table 14.

TABLE 14 Treatment list. The amounts shown were applied twice to all plants. Applied N, Treatment Description lbs N/acre 1 Control 0 2 Composition 1 40 3 Composition 1 80 4 Dry Blood meal 40 5 Dry blood meal 80 Note: Composition 1 (“Semi-humic composition”) is described in Example 1.

Note: Applications were made with added water as needed such that an equal amount of liquid was applied to each pot.

Measurements & Data Analysis

All plants were harvested on Day 29, when plants were about 9-10 inches tall. Plant root length and shoot height was recorded for each plant. Plant roots were carefully washed to remove soil. Each plant was divided into shoot and root, their lengths were recorded, fresh weights were recorded, and then plants were dried at 70° C. for 3 days until constant weight. After drying, plant parts were weighed separately and totaled. Shoots were analyzed for % N by Total Nitrogen via dry combustion.

All data were analyzed by Analysis of Variance (ANOVA). Where significant differences were detected at p<0.10, mean separation was performed using Duncan's new multiple range (MRT) test.

Results and Discussion

TABLE 15 Results of ANOVA for the parameters measured in Example 5. Further Response variable p-value Conclusion Analysis Root length, inches 0.99 No significant None Shoot length, inches 0.25 treatment effect Root fresh weight, g 0.39 Shoot fresh weight, g 0.99 Total fresh weight, g 0.99 Shoot dry weight, g 0.27 Root dry weight, g 0.0005 Treatment effect is Duncan's MRT significant (see FIG. 6) Total dry weight, g 0.095 Primary treatment None (=sum of root + effect appears to shoot) be the effect on roots % N in shoots 0.0001 Treatment effect is Duncan's MRT significant (see FIG. 7)

As shown in Table 15, significant treatment effects were observed at the 5% level on root dry weight and on % N in shoots. Treatment means and Duncan's MRT results for these two parameters are shown in FIGS. 6 and 7.

FIG. 6 shows the results for root dry weight, where columns with different letters are significantly different by Duncan's Multiple Range Test (p=0.05). It can be seen from FIG. 6 that pepper roots treated with Composition 1 had significantly greater root biomass than those treated with blood meal alone at either Nitrogen rate (Treatments 4-5). Root biomass is a good indicator of plant growth and is one predictor of eventual plant yield.

FIG. 7 shows the percent nitrogen in shoot biomass of peppers at harvest across treatments. Columns with different letters are significantly different by Duncan's Multiple Range Test. (p=0.01). It can be seen from FIG. 7 that shoot nitrogen content of pepper plants treated with Composition 1 had significantly greater nitrogen content than blood meal by itself at both rates of nitrogen (Treatments 4-5). It is well known that plant nitrogen content is correlated to subsequent plant development and yield. It should be noted that this trial was not designed to measure pepper yield.

Overall, FIGS. 6 and 7 show that Composition 1 was superior to blood meal alone (Treatments 4 and 5) in certain key plant growth parameters. Therefore, these results support the conclusion that Composition 1 would be a superior source of nitrogen that is readily used by the crop for its growth and development, for use by organic farmers. 

1. A liquid semi-humic composition comprising one or more humic substances which has been chemically interacted with one or more organic non-humic nitrogenous molecules.
 2. The semi-humic composition of claim 1, wherein the one or more organic non-humic nitrogenous molecules comprise proteins, peptides, amines, amides and/or amino acids.
 3. The semi-humic composition of claim 1, wherein the one or more organic non-humic nitrogenous molecules are derived from fresh and/or partially decomposed plant material, animal manure, animal and/or fish parts.
 4. The semi-humic composition of claim 1, wherein the one or more organic non-humic nitrogenous molecules are derived from blood meal, intestines, bone meals, feathers, crustacean, microbial, bacterial, protozoan, chromistan, fungal biomass, fresh corn meal, soy meal and/or other plant seed materials.
 5. The semi-humic composition of claim 1, wherein the one or more organic non-humic nitrogenous molecules comprise peptides.
 6. The semi-humic composition of claim 1, wherein the one or more organic non-humic nitrogenous molecules are covalently bonded to the humic sub stance.
 7. The semi-humic composition of claim 1, wherein the semi-humic composition comprises at least about 5%, or at least about 10% or at least about 12% humic acid as calculated via the CDFA method.
 8. The semi-humic composition of claim 1, wherein the semi-humic composition comprises at least about 3% nitrogen.
 9. The semi-humic composition of claim 1, characterized as having from about 30 to about 40% of molecules classified as lipid, protein and other aliphatic by FTICR-MS.
 10. The semi-humic composition of claim 9, further characterized as having from about 25 to about 30% of molecules classified as lignin by FTICR-MS.
 11. The semi-humic composition of claim 9, wherein the semi-humic material is further characterized by FTICR-MS as having from about 5 to about 10% of molecules classified as condensed aromatic.
 12. The semi-humic composition of claim 1, characterized as having about 37% of molecules classified as lipid, protein and other aliphatic by FTICR-MS.
 13. The semi-humic composition of claim 1, characterized as having about 26% of molecules classified as lignin by FTICR-MS.
 14. The semi-humic composition of claim 1, characterized as having about 9% of molecules classified as condensed aromatic by FTICR-MS.
 15. A semi-humic composition substantially characterized by the Van Krevelen Diagram shown in FIG. 3B.
 16. A semi-humic composition substantially characterized by the Van Krevelen Diagram shown in FIG. 4B.
 17. A process for preparing the semi-humic composition of claim 1, said process comprising the steps of: (a) heating an aqueous composition of an organic non-humic nitrogenous source in the presence of a base to a temperature of about 100° F. or higher; (b) adding leonardite ore or other soft brown coal to the composition and mixing to provide a liquid portion and a solids portion; and (c) separating the liquid portion from the solids portion to provide the semi-humic composition.
 18. A process for preparing the semi-humic composition of claim 1, said process comprising the steps of: (a) heating an aqueous composition of leonardite ore or other soft brown coal in the presence of a base to a temperature of about 160° F. or higher to provide a composition having a liquid portion and a solids portion; (b) mixing an organic non-humic nitrogenous source with the composition of step (a) and heating to a temperature of at least about 160° F. for at least about 2 hours, and optionally further removing solids, to provide the semi-humic composition.
 19. The process of claim 18, wherein the process further comprises the step of separating the liquid portion from the solids portion of step (a).
 20. The process of claim 19, wherein the mixing of step (b) comprises mixing the organic non-humic nitrogenous source with the liquid portion of step (a).
 21. The process of claim 18, wherein the base is sodium hydroxide or potassium hydroxide.
 22. The process of claim 18, wherein the organic non-humic nitrogenous source is blood meal, intestines, bone meals, feathers, microbial, bacterial, or fungal biomass.
 23. A semi-humic composition comprising one or more humic substances which has been chemically interacted with one or more organic non-humic nitrogenous molecules, wherein the semi-humic composition is obtained by the process of claim claim
 18. 24. A method of increasing the rate of nitrogen mineralization in soil by at least about 50% after about 2 weeks, comprising applying the semi-humic composition of claim 1 to soil at a concentration of at least about 10 milligrams of semi-humic composition per 100 grams of soil.
 25. A method of increasing the rate of nitrogen mineralization in soil by at least about 50% after about 2 weeks, comprising applying the semi-humic composition of claim 1 at a concentration of at least about 5 to about 1,000 gallons per acre to soil or about 0.25 to about 5 gallons per acre to foliage.
 26. A method of increasing nitrogen content in a crop by at least about 50% at about 4 weeks, comprising applying the semi-humic composition of claim 1 to soil at a concentration of at least about 10 milligrams of semi-humic composition per 100 grams of soil.
 27. A method of increasing nitrogen content in a crop by at least about 50% at about 4 weeks, comprising applying the semi-humic composition of claim 1 at a concentration of at least about 5 to about 1,000 gallons per acre to soil or about 0.25 to about 5 gallons per acre to foliage.
 28. A method of increasing the rate of nitrogen uptake by a crop by at least about 50%, comprising applying the semi-humic composition of claim 1 to soil at a concentration of at least about 10 milligrams of semi-humic composition per 100 grams of soil.
 29. A method of increasing the rate of nitrogen uptake by a crop by at least about 50%, comprising applying the semi-humic composition of claim 1 at a concentration of at least about 5 to about 1,000 gallons per acre to soil or about 0.25 to about 5 gallons per acre to foliage.
 30. A method of enhancing crop growth by at least about 25%, comprising applying the semi-humic composition of claim 1 to soil at a concentration of at least about 10 milligrams of semi-humic composition per 100 grams of soil.
 31. A method of enhancing crop growth by at least about 25%, comprising applying the semi-humic composition of claim 1 at a concentration of at least about 5 to about 1,000 gallons per acre to soil or about 0.25 to about 5 gallons per acre to foliage.
 32. A method of increasing crop yield by at least about 25%, comprising applying the semi-humic composition of claim 1 to soil at a concentration of at least about 10 milligrams of semi-humic composition per 100 grams of soil.
 33. A method of increasing crop yield by at least about 25%, comprising applying the semi-humic composition of claim 1 at a concentration of at least about 5 to about 1,000 gallons per acre to soil or about 0.25 to about 5 gallons per acre to foliage.
 34. The method of claim 1, wherein the applying comprises chemigation. 